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- W1994858811 abstract "Abstract Novel adducts of Mn(II) and Fe(II) saccharinates with imidazole were synthesized and their protonated and deuterated analogues were investigated by the means of FT-IR spectroscopy at room and at liquid-nitrogen boiling temperature. The appearance of the characteristic OH/OD, NH, CO and SO 2 stretching bands was employed together with the earlier spectra–structure correlations to predict certain structural details about the complexes. The IR spectra reveal pronounced structural similarity and possible isomorphism with the Co and Ni adducts of formula [M(C 3 H 4 N 2 ) 4 (H 2 O) 2 ](C 7 H 4 NO 3 S) 2 . There is a single crystallographic type of asymmetrically bonded water molecules in the structure. All saccharinato ions are structurally equal. The O–S–O angles should be similar with those in Mg(sac) 2 ·7H 2 O and Na 3 (sac) 3 ·2H 2 O." @default.
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- W1994858811 date "2001-05-01" @default.
- W1994858811 modified "2023-10-05" @default.
- W1994858811 title "Vibrational studies of the solid imidazole and pyridine adducts of metal(II) saccharinates. Part II. Mn(II) and Fe(II) imidazole saccharinates" @default.
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- W1994858811 doi "https://doi.org/10.1016/s0022-2860(00)00937-6" @default.
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