Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994883388> ?p ?o ?g. }
- W1994883388 endingPage "133" @default.
- W1994883388 startingPage "124" @default.
- W1994883388 abstract "Abstract By using η3-(SCH2CH2SCH2CH2S) (SSS), 2-thiocytosine (HL1) and 5-amino-1,3,4-thiadiazole-2-thiol (HL2) as S-donor ligands two ‘3 + 1’ mixed ligand red oxorhenium(V) complexes of the type [ReO(SSS)(HL1)]Cl (1Cl) and [ReO(SSS)(L2)] (2) have been synthesized. Both 1Cl and 2 have been characterized by C, H and N microanalyses, 1H NMR, FT-IR, UV–Vis spectra and conductivity measurements. The X-ray crystal structures of both 1Cl and 2 have been determined. Electrochemical studies of 1Cl in acetonitrile show four successive one-electron redox couples; while 2 in DMSO displays only two one- electron redox steps. A computational and conceptual Density Functional Theory (DFT) studies have been performed on various (3 + 1) complexes of Re(V). The fully-optimized complexes, 1Cl and 2, adopt geometries that satisfactorily corroborate the X-ray structures. Subsequently these optimized structures were employed to investigate systematically the relative stabilities of various Re(V) complexes with varying ligands having N, O and S donor atoms. The electronic properties of 1Cl and 2 were delved into employing the hybrid STMP TD-DFT method and the results were found to be in good harmony with the experimental observations." @default.
- W1994883388 created "2016-06-24" @default.
- W1994883388 creator A5004924045 @default.
- W1994883388 creator A5011021117 @default.
- W1994883388 creator A5011369979 @default.
- W1994883388 creator A5068236661 @default.
- W1994883388 creator A5073209643 @default.
- W1994883388 creator A5080760869 @default.
- W1994883388 date "2015-01-01" @default.
- W1994883388 modified "2023-09-26" @default.
- W1994883388 title "New mixed ligand oxorhenium(V) complexes of 3-thiapentane-1,5-dithiolato with 2-thiocytosine and 5-amino-1,3,4-thiadiazole-2-thiol: Experiment and theory" @default.
- W1994883388 cites W1501145371 @default.
- W1994883388 cites W1964993103 @default.
- W1994883388 cites W1966182479 @default.
- W1994883388 cites W1966792574 @default.
- W1994883388 cites W1967414543 @default.
- W1994883388 cites W1969660485 @default.
- W1994883388 cites W1973372277 @default.
- W1994883388 cites W1976812707 @default.
- W1994883388 cites W1981368803 @default.
- W1994883388 cites W1981394668 @default.
- W1994883388 cites W1982356449 @default.
- W1994883388 cites W1984145053 @default.
- W1994883388 cites W1990145960 @default.
- W1994883388 cites W1996459114 @default.
- W1994883388 cites W1998722626 @default.
- W1994883388 cites W2008423326 @default.
- W1994883388 cites W2015723183 @default.
- W1994883388 cites W2018613259 @default.
- W1994883388 cites W2022100642 @default.
- W1994883388 cites W2023882993 @default.
- W1994883388 cites W2026559115 @default.
- W1994883388 cites W2032719166 @default.
- W1994883388 cites W2039559098 @default.
- W1994883388 cites W2039848533 @default.
- W1994883388 cites W2042170565 @default.
- W1994883388 cites W2043327592 @default.
- W1994883388 cites W2043351579 @default.
- W1994883388 cites W2044168855 @default.
- W1994883388 cites W2044779828 @default.
- W1994883388 cites W2045920655 @default.
- W1994883388 cites W2046081922 @default.
- W1994883388 cites W2046229956 @default.
- W1994883388 cites W2048825381 @default.
- W1994883388 cites W2058848030 @default.
- W1994883388 cites W2061500702 @default.
- W1994883388 cites W2062404099 @default.
- W1994883388 cites W2068371586 @default.
- W1994883388 cites W2071716604 @default.
- W1994883388 cites W2075604682 @default.
- W1994883388 cites W2077031331 @default.
- W1994883388 cites W2082917109 @default.
- W1994883388 cites W2088027248 @default.
- W1994883388 cites W2089147762 @default.
- W1994883388 cites W2106824077 @default.
- W1994883388 cites W2118181408 @default.
- W1994883388 cites W2124038947 @default.
- W1994883388 cites W2131350133 @default.
- W1994883388 cites W2141805881 @default.
- W1994883388 cites W2146524636 @default.
- W1994883388 cites W2165583123 @default.
- W1994883388 cites W2330026874 @default.
- W1994883388 cites W3105938624 @default.
- W1994883388 cites W4211125560 @default.
- W1994883388 cites W2014079217 @default.
- W1994883388 cites W2064895267 @default.
- W1994883388 doi "https://doi.org/10.1016/j.ica.2014.10.004" @default.
- W1994883388 hasPublicationYear "2015" @default.
- W1994883388 type Work @default.
- W1994883388 sameAs 1994883388 @default.
- W1994883388 citedByCount "15" @default.
- W1994883388 countsByYear W19948833882015 @default.
- W1994883388 countsByYear W19948833882016 @default.
- W1994883388 countsByYear W19948833882017 @default.
- W1994883388 countsByYear W19948833882018 @default.
- W1994883388 countsByYear W19948833882020 @default.
- W1994883388 countsByYear W19948833882021 @default.
- W1994883388 countsByYear W19948833882023 @default.
- W1994883388 crossrefType "journal-article" @default.
- W1994883388 hasAuthorship W1994883388A5004924045 @default.
- W1994883388 hasAuthorship W1994883388A5011021117 @default.
- W1994883388 hasAuthorship W1994883388A5011369979 @default.
- W1994883388 hasAuthorship W1994883388A5068236661 @default.
- W1994883388 hasAuthorship W1994883388A5073209643 @default.
- W1994883388 hasAuthorship W1994883388A5080760869 @default.
- W1994883388 hasConcept C116569031 @default.
- W1994883388 hasConcept C147597530 @default.
- W1994883388 hasConcept C155647269 @default.
- W1994883388 hasConcept C170493617 @default.
- W1994883388 hasConcept C178790620 @default.
- W1994883388 hasConcept C185592680 @default.
- W1994883388 hasConcept C2781324293 @default.
- W1994883388 hasConcept C55493867 @default.
- W1994883388 hasConcept C71240020 @default.
- W1994883388 hasConcept C8010536 @default.
- W1994883388 hasConceptScore W1994883388C116569031 @default.
- W1994883388 hasConceptScore W1994883388C147597530 @default.
- W1994883388 hasConceptScore W1994883388C155647269 @default.