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• W1994885909 abstract "Using first-principles calculations within density functional theory, we study the energetics and kinetics of C nucleation in the early stages of epitaxial graphene growth on three representative stepped metal surfaces: Ir(111), Ru(0001), and Cu(111). We find that on the flat surfaces of Ir(111) and Ru(0001), two C atoms repel each other, while they prefer to form a dimer on Cu(111). Moreover, the step edges on Ir and Ru surfaces cannot serve as effective trapping centers for single C adatoms, but can readily facilitate the formation of C dimers. These contrasting behaviors are attributed to the delicate competition between C-C bonding and C-metal bonding, and a simple generic principle is proposed to predict the nucleation sites of C adatoms on many other metal substrates with the C-metal bond strengths as the minimal inputs." @default.
• W1994885909 created "2016-06-24" @default.
• W1994885909 creator A5005235961 @default.
• W1994885909 creator A5039655176 @default.
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• W1994885909 date "2010-05-06" @default.
• W1994885909 modified "2023-09-30" @default.
• W1994885909 title "Contrasting Behavior of Carbon Nucleation in the Initial Stages of Graphene Epitaxial Growth on Stepped Metal Surfaces" @default.
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• W1994885909 doi "https://doi.org/10.1103/physrevlett.104.186101" @default.
• W1994885909 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20482191" @default.
• W1994885909 hasPublicationYear "2010" @default.
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