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- W1994927082 abstract "Abstract The i.r. spectra of lithium ammonium sulphate have been measured at 463, 300, 170 and 30 K covering all the phases of its structure. The shifts and the splittings of the frequencies of molecular ions have been interpreted in terms of the involved structural changes. The hindering of the reorientational motions of ammonium ion appears to be of the same type in the phases II, III and IV whereas in phase I the reorientational motions look nearly free. For the transition from phase I to phase II the involvement of ammonium ion seems to be more than that of LiOS skeleton while it is the LiOS skeleton which is found responsible for the transitions—phases II–III and III–IV. The LiO 4 tetrahedra are observed to be more distorted in phase III. The sulphate tetrahedra exhibit more angular distortion in phase IV. Evidence has also been found for the presence of hydrogen bonding whose strength increases with the cooling of the crystal." @default.
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- W1994927082 date "1981-01-01" @default.
- W1994927082 modified "2023-09-27" @default.
- W1994927082 title "An i.r. study of the phases of lithium ammonium sulphate" @default.
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- W1994927082 doi "https://doi.org/10.1016/0584-8539(81)80139-0" @default.
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