Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994930232> ?p ?o ?g. }
- W1994930232 endingPage "632" @default.
- W1994930232 startingPage "625" @default.
- W1994930232 abstract "The stereochemistry of the osmium-catalyzed dihydroxylation of a series of chiral allylic amides and carbamates has been studied. The diastereoselectivity of these reactions was found to be dependent upon the solvent and the nitrogen protecting group as well as the geometry and substitution pattern of the olefin substrate. In contrast to the erythro selectivity observed with allylic alcohols, osmylations of the allylic amides and carbamates in this study were threo selective. Stoichiometric osmylations were consistently more selective than the corresponding catalytic reactions. Control experiments suggest this is due to the presence of a second catalytic cycle based upon an osmium glycolate catalyst which accumulates as the reaction proceeds to completion. Double diastereoselective dihydroxylations of allylic carbamates were also briefly examined." @default.
- W1994930232 created "2016-06-24" @default.
- W1994930232 creator A5017806914 @default.
- W1994930232 creator A5037130056 @default.
- W1994930232 creator A5076058258 @default.
- W1994930232 date "1994-04-01" @default.
- W1994930232 modified "2023-10-09" @default.
- W1994930232 title "Diastereoselectivity in the osmium-catalyzed dihydroxylation of allylic amides and carbamates" @default.
- W1994930232 cites W1964995954 @default.
- W1994930232 cites W1969164602 @default.
- W1994930232 cites W1971123029 @default.
- W1994930232 cites W1972139427 @default.
- W1994930232 cites W1973378660 @default.
- W1994930232 cites W1975704067 @default.
- W1994930232 cites W1987965877 @default.
- W1994930232 cites W1990497949 @default.
- W1994930232 cites W1993384219 @default.
- W1994930232 cites W2006807719 @default.
- W1994930232 cites W2007772558 @default.
- W1994930232 cites W2009835609 @default.
- W1994930232 cites W2011827335 @default.
- W1994930232 cites W2011878219 @default.
- W1994930232 cites W2014589460 @default.
- W1994930232 cites W2017372573 @default.
- W1994930232 cites W2026826411 @default.
- W1994930232 cites W2028504300 @default.
- W1994930232 cites W2030862186 @default.
- W1994930232 cites W2038637839 @default.
- W1994930232 cites W2041796969 @default.
- W1994930232 cites W2045115741 @default.
- W1994930232 cites W2056948912 @default.
- W1994930232 cites W2059084439 @default.
- W1994930232 cites W2059136253 @default.
- W1994930232 cites W2059156553 @default.
- W1994930232 cites W2060985304 @default.
- W1994930232 cites W2067582620 @default.
- W1994930232 cites W2068214511 @default.
- W1994930232 cites W2074960707 @default.
- W1994930232 cites W2094046414 @default.
- W1994930232 cites W2137534575 @default.
- W1994930232 cites W2156997087 @default.
- W1994930232 cites W2950211302 @default.
- W1994930232 cites W2950540257 @default.
- W1994930232 cites W2951515408 @default.
- W1994930232 cites W2952927800 @default.
- W1994930232 cites W3004979348 @default.
- W1994930232 cites W4232504170 @default.
- W1994930232 cites W4250839705 @default.
- W1994930232 doi "https://doi.org/10.1016/0957-4166(94)80024-3" @default.
- W1994930232 hasPublicationYear "1994" @default.
- W1994930232 type Work @default.
- W1994930232 sameAs 1994930232 @default.
- W1994930232 citedByCount "35" @default.
- W1994930232 countsByYear W19949302322012 @default.
- W1994930232 countsByYear W19949302322013 @default.
- W1994930232 countsByYear W19949302322014 @default.
- W1994930232 countsByYear W19949302322017 @default.
- W1994930232 crossrefType "journal-article" @default.
- W1994930232 hasAuthorship W1994930232A5017806914 @default.
- W1994930232 hasAuthorship W1994930232A5037130056 @default.
- W1994930232 hasAuthorship W1994930232A5076058258 @default.
- W1994930232 hasConcept C118792377 @default.
- W1994930232 hasConcept C120095180 @default.
- W1994930232 hasConcept C144082473 @default.
- W1994930232 hasConcept C146686406 @default.
- W1994930232 hasConcept C155647269 @default.
- W1994930232 hasConcept C161790260 @default.
- W1994930232 hasConcept C178790620 @default.
- W1994930232 hasConcept C185592680 @default.
- W1994930232 hasConcept C2777672777 @default.
- W1994930232 hasConcept C2780471494 @default.
- W1994930232 hasConcept C51886252 @default.
- W1994930232 hasConcept C540285154 @default.
- W1994930232 hasConcept C555196967 @default.
- W1994930232 hasConceptScore W1994930232C118792377 @default.
- W1994930232 hasConceptScore W1994930232C120095180 @default.
- W1994930232 hasConceptScore W1994930232C144082473 @default.
- W1994930232 hasConceptScore W1994930232C146686406 @default.
- W1994930232 hasConceptScore W1994930232C155647269 @default.
- W1994930232 hasConceptScore W1994930232C161790260 @default.
- W1994930232 hasConceptScore W1994930232C178790620 @default.
- W1994930232 hasConceptScore W1994930232C185592680 @default.
- W1994930232 hasConceptScore W1994930232C2777672777 @default.
- W1994930232 hasConceptScore W1994930232C2780471494 @default.
- W1994930232 hasConceptScore W1994930232C51886252 @default.
- W1994930232 hasConceptScore W1994930232C540285154 @default.
- W1994930232 hasConceptScore W1994930232C555196967 @default.
- W1994930232 hasIssue "4" @default.
- W1994930232 hasLocation W19949302321 @default.
- W1994930232 hasOpenAccess W1994930232 @default.
- W1994930232 hasPrimaryLocation W19949302321 @default.
- W1994930232 hasRelatedWork W1971655534 @default.
- W1994930232 hasRelatedWork W1994930232 @default.
- W1994930232 hasRelatedWork W2020300490 @default.
- W1994930232 hasRelatedWork W2095465893 @default.
- W1994930232 hasRelatedWork W2102558326 @default.
- W1994930232 hasRelatedWork W2102796255 @default.
- W1994930232 hasRelatedWork W2316580842 @default.