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- W1994945246 abstract "Abstract Anodic galvanoluminescence (AG) of Al was established in a number of non-aqueous electrolytes. AG of high purity and silver or copper doped aluminium was investigated during anodization in an aqueous borate electrolyte (ABE) and solutions of ammonium salicylate and ammonium adipinate in dimethylformamide (DMF) and ethylene—glycol (EG). The brightness characteristics proved to be different for the aqueous and the non-aqueous electrolytes. For the latter, the AG-brightness was found to be about hundred times higher than that for pure Al in ABE, and depended neither on the ionogen concentration, nor on the metal purity. Moreover, the AG-spectrum in the non-aqueous electrolytes proved to be characteristic for the nature of the solvent (DMF and EG). On the contrary, in ABE the well-known increase of AG-brightness with doped Al was observed, the spectra having been found characteristics for the metal impurity. The findings are explained on the basis of a hypothesis about the origin of liminescent centers. According to it, both the metal impurities and the ions or molecules from the electrolyte can penetrate into the anodic film, acting there as liminescent centers. Brightness and spectral distribution of AG will then be determined by those centers, which supply the prevailing light flux." @default.
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- W1994945246 date "1978-11-01" @default.
- W1994945246 modified "2023-09-24" @default.
- W1994945246 title "Galvanoluminescence of aluminium during anodization in non-dissolving electrolytes" @default.
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- W1994945246 doi "https://doi.org/10.1016/0013-4686(78)85074-9" @default.
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