Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994966981> ?p ?o ?g. }
Showing items 1 to 81 of
81
with 100 items per page.
- W1994966981 endingPage "38" @default.
- W1994966981 startingPage "31" @default.
- W1994966981 abstract "The ν2 infrared fundamental of the transient molecule formyl chloride, HCOCl, has been recorded at high resolution. Detailed assignments of the rotational structure have been made for both HCO 35Cl and HCO 37Cl. The ν2 band, whose origin is at 1784.1377 cm−1 in HCO 35Cl, is predominantly A type with a very weak B-type component. Numerous excited state perturbations occur throughout the band, caused mainly by ‖ΔKa‖=2 Fermi resonance and ‖ΔKa‖=1 Coriolis interactions with the 3151 vibrational state. Even though no ‘‘extra’’ lines resulting from the perturbations could be assigned, a complete analysis of the perturbed rotational structure has been possible. Accurate molecular constants for both the ‘‘bright’’ perturbed 21 state and the ‘‘dark’’ 3151 perturbing state have been obtained, using a Hamiltonian which includes both the Fermi and Coriolis interactions; only two interaction parameters are needed, one for each mechanism. Further perturbations at high Ka are assigned to Coriolis interactions with the 5261 level." @default.
- W1994966981 created "2016-06-24" @default.
- W1994966981 creator A5072758376 @default.
- W1994966981 creator A5081037178 @default.
- W1994966981 creator A5084859397 @default.
- W1994966981 date "1994-07-01" @default.
- W1994966981 modified "2023-09-26" @default.
- W1994966981 title "Determination of the spectroscopic constants of a dark vibrational state: Fermi and Coriolis perturbations in the ν2 band of formyl chloride" @default.
- W1994966981 cites W1973410256 @default.
- W1994966981 cites W1974415806 @default.
- W1994966981 cites W1981495404 @default.
- W1994966981 cites W1987164076 @default.
- W1994966981 cites W1988492613 @default.
- W1994966981 cites W2027385638 @default.
- W1994966981 cites W2028925602 @default.
- W1994966981 cites W2033018809 @default.
- W1994966981 cites W2034026750 @default.
- W1994966981 cites W2044293847 @default.
- W1994966981 cites W2046025157 @default.
- W1994966981 cites W2050691740 @default.
- W1994966981 cites W2050977594 @default.
- W1994966981 cites W2062174618 @default.
- W1994966981 cites W2064094165 @default.
- W1994966981 cites W2068216808 @default.
- W1994966981 cites W2075320078 @default.
- W1994966981 cites W2127582841 @default.
- W1994966981 cites W2332705715 @default.
- W1994966981 doi "https://doi.org/10.1063/1.468191" @default.
- W1994966981 hasPublicationYear "1994" @default.
- W1994966981 type Work @default.
- W1994966981 sameAs 1994966981 @default.
- W1994966981 citedByCount "15" @default.
- W1994966981 crossrefType "journal-article" @default.
- W1994966981 hasAuthorship W1994966981A5072758376 @default.
- W1994966981 hasAuthorship W1994966981A5081037178 @default.
- W1994966981 hasAuthorship W1994966981A5084859397 @default.
- W1994966981 hasConcept C121332964 @default.
- W1994966981 hasConcept C126255220 @default.
- W1994966981 hasConcept C130787639 @default.
- W1994966981 hasConcept C158355884 @default.
- W1994966981 hasConcept C181500209 @default.
- W1994966981 hasConcept C184779094 @default.
- W1994966981 hasConcept C185592680 @default.
- W1994966981 hasConcept C186769553 @default.
- W1994966981 hasConcept C26873012 @default.
- W1994966981 hasConcept C2776565987 @default.
- W1994966981 hasConcept C33923547 @default.
- W1994966981 hasConcept C62520636 @default.
- W1994966981 hasConceptScore W1994966981C121332964 @default.
- W1994966981 hasConceptScore W1994966981C126255220 @default.
- W1994966981 hasConceptScore W1994966981C130787639 @default.
- W1994966981 hasConceptScore W1994966981C158355884 @default.
- W1994966981 hasConceptScore W1994966981C181500209 @default.
- W1994966981 hasConceptScore W1994966981C184779094 @default.
- W1994966981 hasConceptScore W1994966981C185592680 @default.
- W1994966981 hasConceptScore W1994966981C186769553 @default.
- W1994966981 hasConceptScore W1994966981C26873012 @default.
- W1994966981 hasConceptScore W1994966981C2776565987 @default.
- W1994966981 hasConceptScore W1994966981C33923547 @default.
- W1994966981 hasConceptScore W1994966981C62520636 @default.
- W1994966981 hasIssue "1" @default.
- W1994966981 hasLocation W19949669811 @default.
- W1994966981 hasOpenAccess W1994966981 @default.
- W1994966981 hasPrimaryLocation W19949669811 @default.
- W1994966981 hasRelatedWork W1914058719 @default.
- W1994966981 hasRelatedWork W1978856795 @default.
- W1994966981 hasRelatedWork W1991575339 @default.
- W1994966981 hasRelatedWork W1993542064 @default.
- W1994966981 hasRelatedWork W2038599716 @default.
- W1994966981 hasRelatedWork W2042540006 @default.
- W1994966981 hasRelatedWork W2060051479 @default.
- W1994966981 hasRelatedWork W3101860255 @default.
- W1994966981 hasRelatedWork W3102605247 @default.
- W1994966981 hasRelatedWork W3106235591 @default.
- W1994966981 hasVolume "101" @default.
- W1994966981 isParatext "false" @default.
- W1994966981 isRetracted "false" @default.
- W1994966981 magId "1994966981" @default.
- W1994966981 workType "article" @default.