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- W1994983857 abstract "An enantioselective synthesis of mitosane core (-)-1 has been achieved. Key steps include a rapid assembly of a key eight-membered-ring intermediate employing ring-closing metathesis. Kinetic resolution of an advanced secondary alcohol was then accomplished by using a peptide-based asymmetric acyl transfer catalyst that was discovered from a parallel screen of catalyst candidates. Optically pure material was then converted to the mitosane core, which was the subject of additional studies on the selective modification to produce several substituted compounds containing a mitosane ring system." @default.
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- W1994983857 date "2003-02-25" @default.
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- W1994983857 title "Enantioselective Synthesis of an Aziridinomitosane and Selective Functionalizations of a Key Intermediate" @default.
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- W1994983857 doi "https://doi.org/10.1021/jo0269013" @default.
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