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- W1994995498 abstract "Abstract The mechanisms underlying chiral recognition of enantiomer separation using a conformationally rigid chiral stationary phase (CSP 2) derived from N-3,5-dinitrobenzoyl (DNB) α-amino-ϵ-carprolactam, a CSP structurally related to DNB leucine derived CSP 1, were investigated. Chromatographic comparisons of the resolution for two typical types of analytes were made on CSPs 1 and 2. For enantioseparation of N-acyl derivatives of 1-(1-or 2-naphthyl)ethylamine, all separation factors for DNB leucine derived CSP 1 were greater than those for DNB ϵ-carprolactam derived CSP 2. On the other hand, all separation factors for CSP 2 were much greater than those for CSP 1 when resolving DNB leucine derivatives. In any case, the overall chiral recognition mechanism of CSP 2 might be similar to that of CSP 1. However, it is thought that the conformationally rigid structure and/or enhanced electron density of the carbonyl group as a tertiary amide of CSP 2 could be responsible for different levels of chiral recognition relative to CSP 1, depending upon the analytes examined. Keywords: 3,5-dinitrobenzoyl leucineα-amino-ϵ-carprolactamchiral recognitionchiral stationary phaseconformationally rigidenantiomer separation Notes Color versions of one or more of the figures in the article can be found online at www.tandfonline.com/ljlc." @default.
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- W1994995498 date "2014-06-11" @default.
- W1994995498 modified "2023-09-23" @default.
- W1994995498 title "CHIRAL RECOGNITION USING A CONFORMATIONALLY RIGID CHIRAL STATIONARY PHASE DERIVED FROM α-AMINO-ϵ-CARPROLACTAM" @default.
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- W1994995498 doi "https://doi.org/10.1080/10826076.2013.807467" @default.
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