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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1994999910> ?p ?o ?g. }

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• W1994999910 abstract "An X-ray structure of (thiourea)pentaammineruthenium shows an sp3 sulfur atom bonded to Ru(III). Bond lengths and angles reveal substantial electronic reorganization in the thiourea with a significant contribution to the electronic structure from the resonance hybrid [(NH3)5Ru(-S−C(NH2+)NH2)]3+. Deprotonation (pKa 10.8) activates this polarized thiourea ligand to hydrolysis, oxidation, and formation of the diamagnetic dimer [((NH3)5RuIII−S−S−RuIII(NH3)5]4+. This may be another pathway to metal disulfide formation in biological systems." @default.
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• W1994999910 date "1997-05-01" @default.
• W1994999910 modified "2023-10-03" @default.
• W1994999910 title "Activation of Thiourea Bound through Sulfur to Pentaammineruthenium(III): Structure and Reactivity" @default.
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• W1994999910 doi "https://doi.org/10.1021/ic9611397" @default.
• W1994999910 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11669854" @default.
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