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• W1995032421 endingPage "R10606" @default.
• W1995032421 startingPage "R10603" @default.
• W1995032421 abstract "Structural phase transitions of germanium at pressures up to 190 GPa have been investigated by means of angle-dispersive x-ray powder diffraction using synchrotron radiation. Near 100 GPa the primitive hexagonal modification of Ge transforms to an orthorhombic phase with 16 atoms per unit cell. The results of full-profile Rietveld refinements in space group $mathrm{Cmca}$ indicate that the orthorhombic modification of Ge is isotypic to the phase Si-VI. Near 160--180 GPa Ge undergoes a transition to a structure assigned as hexagonal close packed (hcp). Ab initio calculations of pressure-dependent enthalpies and optimized structural parameters are presented for different structures of Ge. The calculated results clearly support the observed occurrence of the $mathrm{Cmca}$ structure in Ge." @default.
• W1995032421 created "2016-06-24" @default.
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• W1995032421 date "2000-10-15" @default.
• W1995032421 modified "2023-10-17" @default.
• W1995032421 title "High-pressure<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>Cmca</mml:mi></mml:math>and hcp phases of germanium" @default.
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• W1995032421 doi "https://doi.org/10.1103/physrevb.62.r10603" @default.
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