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- W1995044721 abstract "Abstract A detailed study was carried out to investigate the origin of the peak‐splitting phenomena in on‐column concentration‐micellar electrokinetic capillary chromatography for aqueous sample solution. The system studied was a basic phosphate and borax mixed buffer with sodium dodecyl sulfate (SDS) as micellar phase. Phenol, benzyl alcohol, phenyl ethanol, salicylic acid, and p‐hydroxy benzyl acid were selected as the analytes. Several factors that affect peak splitting were investigated. The injection time, SDS micellar concentration, hydrophobicity of the analytes, and analytes concentration were the most important factors. A hypothesis was proposed to explain the peak‐splitting phenomena. Several means to avoid peak‐splitting phenomena were proposed, such as controlling sample injection time and hydrophobicity of the analyte, decreasing SDS concentration and increasing sample concentration. However, the most practical method for avoiding peak splitting was to control the sample injection time." @default.
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- W1995044721 date "2005-09-01" @default.
- W1995044721 modified "2023-09-26" @default.
- W1995044721 title "An Insight into Peak‐Splitting Phenomenon in On‐Column Concentration‐Micellar Electrokinetic Capillary Chromatography for Aqueous Sample Solution" @default.
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- W1995044721 doi "https://doi.org/10.1080/00032710500232851" @default.
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