FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995045620> ?p ?o ?g. }

• W1995045620 endingPage "10555" @default.
• W1995045620 startingPage "10542" @default.
• W1995045620 abstract "We investigated the possible role of binary oxides associating Sb and Mo in the synergetic effects between physically mixed MoO3 and α-Sb2O4 in the selective oxidation of isobutene to methacrolein. The catalytic behavior of three Sb−Mo−O phasesSb2MoO6 on one hand, a mixture of Sb2Mo10O31 and Sb4Mo10O31 on the other handwas investigated. The samples were characterized using X-ray diffraction (XRD), confocal laser Raman microscopy, specific area measurements, and scanning electron microscopy. Additional in situ high-temperature XRD was also performed. At similar conversions of isobutene, the selectivities to methacrolein for the Sb−Mo−O phases were always lower than those of mixtures of MoO3 with α-Sb2O4 with the same atomic compositions. A second result was that the three Sb−Mo−O phases were unstable in the conditions of reaction and tended to decompose to simple molybdenum and antimony oxides. An improvement of the catalytic performances of the Sb−Mo−O catalysts occurred in parallel to their decomposition. Some apparent cooperation effects were observed for mechanical mixtures of the Sb−Mo−O phases with MoO3 or α-Sb2O4. These effects are actually related to the decomposition of the Sb−Mo−O phases and are due to the cooperation between MoO3 and α-Sb2O4 formed at their surface. The spontaneous decomposition of the Sb−Mo−O phases shows that these phases cannot form in operandi (during the catalytic reaction) starting from the simple oxides. Consequently, this shows that they cannot be the real most performant phases in the mixtures of MoO3 with α-Sb2O4 and hence that they cannot be at the origin of the synergism between the simple oxides." @default.
• W1995045620 created "2016-06-24" @default.
• W1995045620 creator A5004182897 @default.
• W1995045620 creator A5025959444 @default.
• W1995045620 creator A5034907291 @default.
• W1995045620 creator A5043185619 @default.
• W1995045620 creator A5046412267 @default.
• W1995045620 date "1998-12-01" @default.
• W1995045620 modified "2023-09-26" @default.
• W1995045620 title "Catalytic Performances and Stability of Three Sb−Mo−O Phases in the Selective Oxidation of Isobutene to Methacrolein" @default.
• W1995045620 cites W163351874 @default.
• W1995045620 cites W176583788 @default.
• W1995045620 cites W1971650088 @default.
• W1995045620 cites W1982824850 @default.
• W1995045620 cites W1996210656 @default.
• W1995045620 cites W2011988535 @default.
• W1995045620 cites W2012530053 @default.
• W1995045620 cites W202548399 @default.
• W1995045620 cites W2028643506 @default.
• W1995045620 cites W2031778762 @default.
• W1995045620 cites W2041202435 @default.
• W1995045620 cites W2055036925 @default.
• W1995045620 cites W2062936913 @default.
• W1995045620 cites W2079222059 @default.
• W1995045620 cites W2152851483 @default.
• W1995045620 doi "https://doi.org/10.1021/jp983232h" @default.
• W1995045620 hasPublicationYear "1998" @default.
• W1995045620 type Work @default.
• W1995045620 sameAs 1995045620 @default.
• W1995045620 citedByCount "25" @default.
• W1995045620 countsByYear W19950456202013 @default.
• W1995045620 countsByYear W19950456202016 @default.
• W1995045620 countsByYear W19950456202019 @default.
• W1995045620 countsByYear W19950456202020 @default.
• W1995045620 countsByYear W19950456202023 @default.
• W1995045620 crossrefType "journal-article" @default.
• W1995045620 hasAuthorship W1995045620A5004182897 @default.
• W1995045620 hasAuthorship W1995045620A5025959444 @default.
• W1995045620 hasAuthorship W1995045620A5034907291 @default.
• W1995045620 hasAuthorship W1995045620A5043185619 @default.
• W1995045620 hasAuthorship W1995045620A5046412267 @default.
• W1995045620 hasConcept C113196181 @default.
• W1995045620 hasConcept C120665830 @default.
• W1995045620 hasConcept C121332964 @default.
• W1995045620 hasConcept C124681953 @default.
• W1995045620 hasConcept C127413603 @default.
• W1995045620 hasConcept C147789679 @default.
• W1995045620 hasConcept C159985019 @default.
• W1995045620 hasConcept C161790260 @default.
• W1995045620 hasConcept C166940927 @default.
• W1995045620 hasConcept C178790620 @default.
• W1995045620 hasConcept C179104552 @default.
• W1995045620 hasConcept C185592680 @default.
• W1995045620 hasConcept C192562407 @default.
• W1995045620 hasConcept C26771246 @default.
• W1995045620 hasConcept C2775968528 @default.
• W1995045620 hasConcept C2780115832 @default.
• W1995045620 hasConcept C40003534 @default.
• W1995045620 hasConcept C42360764 @default.
• W1995045620 hasConcept C521977710 @default.
• W1995045620 hasConcept C541565711 @default.
• W1995045620 hasConcept C549387045 @default.
• W1995045620 hasConceptScore W1995045620C113196181 @default.
• W1995045620 hasConceptScore W1995045620C120665830 @default.
• W1995045620 hasConceptScore W1995045620C121332964 @default.
• W1995045620 hasConceptScore W1995045620C124681953 @default.
• W1995045620 hasConceptScore W1995045620C127413603 @default.
• W1995045620 hasConceptScore W1995045620C147789679 @default.
• W1995045620 hasConceptScore W1995045620C159985019 @default.
• W1995045620 hasConceptScore W1995045620C161790260 @default.
• W1995045620 hasConceptScore W1995045620C166940927 @default.
• W1995045620 hasConceptScore W1995045620C178790620 @default.
• W1995045620 hasConceptScore W1995045620C179104552 @default.
• W1995045620 hasConceptScore W1995045620C185592680 @default.
• W1995045620 hasConceptScore W1995045620C192562407 @default.
• W1995045620 hasConceptScore W1995045620C26771246 @default.
• W1995045620 hasConceptScore W1995045620C2775968528 @default.
• W1995045620 hasConceptScore W1995045620C2780115832 @default.
• W1995045620 hasConceptScore W1995045620C40003534 @default.
• W1995045620 hasConceptScore W1995045620C42360764 @default.
• W1995045620 hasConceptScore W1995045620C521977710 @default.
• W1995045620 hasConceptScore W1995045620C541565711 @default.
• W1995045620 hasConceptScore W1995045620C549387045 @default.
• W1995045620 hasIssue "51" @default.
• W1995045620 hasLocation W19950456201 @default.
• W1995045620 hasOpenAccess W1995045620 @default.
• W1995045620 hasPrimaryLocation W19950456201 @default.
• W1995045620 hasRelatedWork W1534203644 @default.
• W1995045620 hasRelatedWork W2016658611 @default.
• W1995045620 hasRelatedWork W2057808024 @default.
• W1995045620 hasRelatedWork W2354157448 @default.
• W1995045620 hasRelatedWork W2366274717 @default.
• W1995045620 hasRelatedWork W2389992402 @default.
• W1995045620 hasRelatedWork W2593445078 @default.
• W1995045620 hasRelatedWork W2748952813 @default.
• W1995045620 hasRelatedWork W928999388 @default.
• W1995045620 hasRelatedWork W947801468 @default.
• W1995045620 hasVolume "102" @default.

• next