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- W1995045828 abstract "Two ferrocenylacetylene dimetal carbonyl clusters μ-FcCCHCo(CO)3M(CO)2Cp (2, M=Mo; 3, M=W) were obtained from the reactions of the precursor μ-FcCCHCo2(CO)61 with metal exchange reagents NaM(CO)3Cp in THF under reflux. The dimetal compounds 1, 2, and 3 can further react with Fe2(CO)9 in the presence of benzylideneacetone (BDA) to give the corresponding μ3-ferrocenylvinylidene bridged trimetal clusters μ3-FcCHCFeCo2(CO)94 and μ3-FcCHCFeCoM(CO)8Cp (5, M=Mo; 6, M=W), respectively, probably through the formation of the intermediate (BDA)Fe(CO)3 which acts as an Fe(CO)3 transfer-reagent. The new compounds 2–6 were characterized by C/H analysis, IR and 1H-NMR spectrocopies. The molecular structures of 2 and 4 were determined by X-ray structural analysis. 2 is triclinic with space group P1̄ (#2), a=8.733(2) Å, b=14.870(3) Å, c=8.200(2) Å, α=92.77(2)°, β=101.78(2)°, γ=78.41(2)°, V=1021.2(4) Å3, and Z=2; final R=0.025, Rw=0.034 for 2988 reflections. Cluster 4 is orthorhombic with space group P212121 (#19), a=12.186(5) Å, b=14.870(5) Å, c=7.800(6) Å, V=2340(2) Å3 and Z=4; final R=0.062, Rw=0.065 for 2401 reflections." @default.
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- W1995045828 date "1998-11-01" @default.
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- W1995045828 title "Synthesis and expansion reaction of ferrocenylacetylene dimetal carbonyl compounds. The molecular structures of μ -FcCCHCoMo(CO) 5 Cp and μ 3 -FcCHCFeCo 2 (CO) 9" @default.
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- W1995045828 doi "https://doi.org/10.1016/s0022-328x(98)00813-4" @default.
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