FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995082042> ?p ?o ?g. }

• W1995082042 endingPage "13229" @default.
• W1995082042 startingPage "13217" @default.
• W1995082042 abstract "Abstract A series of new mononuclear and carboranylcarboxylate‐bridged dinuclear copper(II) compounds containing the 1‐CH 3 ‐2‐CO 2 H‐1,2‐ closo ‐C 2 B 10 H 10 carborane ligand ( L H) has been synthesized. Reaction of different copper salts with L H at room temperature leads to dinuclear compounds of the general formula [Cu 2 (μ‐ L ) 4 ( L t ) 2 ] ( L t =thf ( 1 ), L t =H 2 O ( 1′ )). The reaction of 1 and 1′ with different terminal pyridyl (py) ligands leads to the formation of a series of structurally analogous complexes by substitution of the terminal ligand thf or H 2 O ( L t =py ( 2 ), p ‐CF 3 ‐py ( 3 ), p ‐CH 3 ‐py ( 4 ), pz ( 6 ), and 4,4′‐bpy ( 7 )), which maintain the structural Cu 2 (μ‐O 2 CR) 4 core in the majority of the cases except for o ‐(CH 3 ) 2 ‐py, where a mononuclear compound ( 5 ) is exclusively obtained. These compounds have been characterized through analytical, spectroscopic (NMR, IR, UV‐visible, ESI‐MS) and magnetic techniques. X‐ray structural analysis revealed a paddle‐wheel structure for the dinuclear compounds, with a square‐pyramidal geometry around each copper ion and the carboranylcarboxylate ions bridging two copper atoms in syn – syn mode. The mononuclear complex obtained with the o ‐(CH 3 ) 2 ‐py ligand presents a square‐planar structure, in which the carboranylcarboxylate ligand adopts a monodentate coordination mode. The magnetic properties of the dinuclear compounds 1 , 3 , 4 , and 6 show a strong antiferromagnetic coupling in all cases ( J =−261 ( 1 ), −255 ( 3 ), −241 ( 4 ), −249 cm −1 ( 6 )). Computational studies based on hybrid density functional methods have been used to study the magnetic properties of the complexes and also to evaluate their relative stability on the basis of the strength of the bond between each Cu II and the terminal ligand." @default.
• W1995082042 created "2016-06-24" @default.
• W1995082042 creator A5005905852 @default.
• W1995082042 creator A5031568797 @default.
• W1995082042 creator A5035172341 @default.
• W1995082042 creator A5038806719 @default.
• W1995082042 creator A5050334426 @default.
• W1995082042 creator A5056424118 @default.
• W1995082042 creator A5064283701 @default.
• W1995082042 creator A5066773114 @default.
• W1995082042 creator A5084168197 @default.
• W1995082042 date "2011-10-18" @default.
• W1995082042 modified "2023-10-01" @default.
• W1995082042 title "Design of Dinuclear Copper Species with Carboranylcarboxylate Ligands: Study of Their Steric and Electronic Effects" @default.
• W1995082042 cites W1598543635 @default.
• W1995082042 cites W1965838160 @default.
• W1995082042 cites W1966883440 @default.
• W1995082042 cites W1971361510 @default.
• W1995082042 cites W1972677469 @default.
• W1995082042 cites W1977885757 @default.
• W1995082042 cites W1984659353 @default.
• W1995082042 cites W1985820681 @default.
• W1995082042 cites W1988103615 @default.
• W1995082042 cites W1993231807 @default.
• W1995082042 cites W1994336812 @default.
• W1995082042 cites W1995850710 @default.
• W1995082042 cites W1999304304 @default.
• W1995082042 cites W2000296205 @default.
• W1995082042 cites W2004116821 @default.
• W1995082042 cites W2004863592 @default.
• W1995082042 cites W2005256937 @default.
• W1995082042 cites W2006486519 @default.
• W1995082042 cites W2007868479 @default.
• W1995082042 cites W2007903081 @default.
• W1995082042 cites W2012186669 @default.
• W1995082042 cites W2017218551 @default.
• W1995082042 cites W2018223635 @default.
• W1995082042 cites W2020145177 @default.
• W1995082042 cites W2021834633 @default.
• W1995082042 cites W2022085591 @default.
• W1995082042 cites W2023271753 @default.
• W1995082042 cites W2025175867 @default.
• W1995082042 cites W2036237464 @default.
• W1995082042 cites W2036507803 @default.
• W1995082042 cites W2037788327 @default.
• W1995082042 cites W2037867633 @default.
• W1995082042 cites W2038491840 @default.
• W1995082042 cites W2040007933 @default.
• W1995082042 cites W2042187926 @default.
• W1995082042 cites W2044013617 @default.
• W1995082042 cites W2044901804 @default.
• W1995082042 cites W2045952721 @default.
• W1995082042 cites W2046704339 @default.
• W1995082042 cites W2048609870 @default.
• W1995082042 cites W2049350055 @default.
• W1995082042 cites W2049599318 @default.
• W1995082042 cites W2050202517 @default.
• W1995082042 cites W2050272591 @default.
• W1995082042 cites W2050648248 @default.
• W1995082042 cites W2051089405 @default.
• W1995082042 cites W2054184444 @default.
• W1995082042 cites W2056965935 @default.
• W1995082042 cites W2059376925 @default.
• W1995082042 cites W2061391565 @default.
• W1995082042 cites W2063378958 @default.
• W1995082042 cites W2065758065 @default.
• W1995082042 cites W2068839847 @default.
• W1995082042 cites W2072776117 @default.
• W1995082042 cites W2072877023 @default.
• W1995082042 cites W2073647944 @default.
• W1995082042 cites W2073956744 @default.
• W1995082042 cites W2076187208 @default.
• W1995082042 cites W2077514425 @default.
• W1995082042 cites W2078444809 @default.
• W1995082042 cites W2082332887 @default.
• W1995082042 cites W2082443270 @default.
• W1995082042 cites W2086957099 @default.
• W1995082042 cites W2089633428 @default.
• W1995082042 cites W2092761599 @default.
• W1995082042 cites W2093641361 @default.
• W1995082042 cites W2105257915 @default.
• W1995082042 cites W2106756917 @default.
• W1995082042 cites W2120667020 @default.
• W1995082042 cites W2124097814 @default.
• W1995082042 cites W2137390070 @default.
• W1995082042 cites W2141417956 @default.
• W1995082042 cites W2143981217 @default.
• W1995082042 cites W2154968054 @default.
• W1995082042 cites W2160173196 @default.
• W1995082042 cites W2164949457 @default.
• W1995082042 cites W2167908928 @default.
• W1995082042 cites W2168986089 @default.
• W1995082042 cites W2312311550 @default.
• W1995082042 cites W2312375573 @default.
• W1995082042 cites W2315147237 @default.
• W1995082042 cites W2320345610 @default.
• W1995082042 cites W2322107771 @default.
• W1995082042 cites W2327055630 @default.

• next