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- W1995087130 abstract "An oxo- and chloro-bridged dinuclear molybdenum(III) ethylenediamine complex, [Mo2(μ-O)(μ-Cl)(en)4]3+, was synthesized by the reaction of [MoCl3(thf)3] with ethylenediamine in DMF. μ-Oxo-μ-alkoxo-bridged dimolybdenum(III) ethylenediamine complexes [Mo2(μ-O)(μ-OMe)(en)4]3+, [Mo2(μ-O)(μ-OEt)(en)4]3+, and [Mo2(μ-O)(μ-OPr)(en)4]3+ were obtained by reactions of the mononuclear complex with ethylenediamine in methanol, ethanol, and propanol, respectively, where each solution contained LiBr. Bridged dimeric structures of these complexes were determined by X-ray crystallography. In an acidic aqueous solution, these oxo-bridged complexes underwent protonation on the bridging oxygen atoms and changes to the corresponding hydroxo-bridged complexes. Cyclic voltammetric measurements (pH 1.0–10.0) of complexes [Mo2(μ-O)(μ-Cl)(en)4]3+, [Mo2(μ-O)(μ-OMe)(en)4]3+, and [Mo2(μ-O)(μ-OEt)(en)4]3+ clearly showed that, accompanied by the oxidation of the complex, the coordinated amine is deprotonated, and the complex becomes a c..." @default.
- W1995087130 created "2016-06-24" @default.
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- W1995087130 date "2003-06-01" @default.
- W1995087130 modified "2023-10-16" @default.
- W1995087130 title "Synthesis, Structure and Proton-Coupled Electron Transfer of μ-Oxo-μ-chloro and μ-Oxo-μ-alkoxo Dimeric Molybdenum(III) Ethylenediamine Complexes" @default.
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- W1995087130 doi "https://doi.org/10.1246/bcsj.76.1155" @default.
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