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- W1995090134 abstract "Abstract The acetone adduct of trirhenium nonachloride, Re3Cl9 (acet)3, where acet=acetone, reacts in acetone solution at room temperature with tetrabutylammonium chalcogenides [N(C4H9)4]2E, where E=S, Se and Te, producing the tetrabutylammonium salts of the new cluster anions [Re3 (μ3-E) (μ2-Cl)3Cl6]2−. In the crystallographically determined structures of these compounds, triangles of rhenium atoms are capped by single chalcogen atoms, giving anions of near C3v symmetry. The compound where E=S is also formed in the reaction of Re3Cl9 with [N(C4H9)4]2 [MoS4] by sulfide transfer." @default.
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- W1995090134 date "1998-11-01" @default.
- W1995090134 modified "2023-09-27" @default.
- W1995090134 title "Synthesis and X-ray crystal structures of new trirhenium nonachloride chalcogenide clusters" @default.
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- W1995090134 doi "https://doi.org/10.1016/s0277-5387(98)00248-4" @default.
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