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- W1995139030 abstract "Intramolecular excimer formation has been investigated for three polystyrene model molecules: 2,4-diphenylpentane, 2,4,6-triphenylheptane and 2,4,6,8-tetraphenylnonane. The results show that isotactic conformations are more favourable for excimer formation than syndiotactic. A high efficiency of excimer sampling is observed for the isotactic forms of the three and four-units polystyrene model molecules with respect to the two-unit model compound. On étudie la formation d'excimères intramoléculaires dans trois molécules modèles du polystyrène: diphényl-2,4 pentane, triphényl-2,4,6 heptane et tétraphényl-2,4,6,8 nonane. Les résultats montrent que les conformations isotactiques sont plus favorables à la formation d'excimère que les conformations syndiotactiques. D'autre part, le rendement quantique de formation d'excimère est plus important dans les formes isotactiques du triphénylheptane et tétraphénylnonane que dans celle du diphénylpentane." @default.
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- W1995139030 date "1977-01-01" @default.
- W1995139030 modified "2023-09-25" @default.
- W1995139030 title "Intramolecular excimer formation in polystyrene model molecules" @default.
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- W1995139030 doi "https://doi.org/10.1016/0014-3057(77)90158-6" @default.
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