Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995141106> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W1995141106 endingPage "81" @default.
- W1995141106 startingPage "77" @default.
- W1995141106 abstract "The title compounds have been prepared from reactions of Co2(CO)6(μ-HOR2CC2R′) or Co2(CO)6(μ-HOR2CC2CR2OH) complexes with Fe(CO)5 in acetone. In the latter set of reactions the homobimetallic butatriene compounds, Fe2(CO)6-(μ-R2CCCCR2), are also obtained. The striking feature of these reactions is the ability of Fe(CO)5 to dehydroxylate the organic moiety and to replace a Co(CO)3 unit forming mixed iron-cobalt derivatives. A direct interaction between the iron and the carbon atom, originally bearing the lost -OH group, is evident from the bulk of the spectroscopic data; thus the organic chain acts as an overall 5 electron donor, according to the E.A.N. formalism. The heterobimetallic compounds have been characterized by elemental analysis, mass spectrometry, IR spectroscopy and NMR studies. For the phosphine derivative FeCo(CO)5(PPh3)(H2CC2OH) a crudely refined X-ray analysis has been performed." @default.
- W1995141106 created "2016-06-24" @default.
- W1995141106 creator A5017551100 @default.
- W1995141106 creator A5026478219 @default.
- W1995141106 creator A5037217009 @default.
- W1995141106 creator A5038724542 @default.
- W1995141106 date "1983-01-01" @default.
- W1995141106 modified "2023-09-23" @default.
- W1995141106 title "Synthesis and spectroscopic characterization of heterobimetallic (α-alkynyl)iron-cobalt hexacarbonyl complexes, μ-(1-σ, 2-3, η2-R2C-CCR′)][(CO)3Fe-Co(CO)3] and [μ-(1-σ, 2-3, η2-H2C-CCCH2OH)] [(CO)3Fe-Co(CO)2(PPh3)]" @default.
- W1995141106 cites W1967678080 @default.
- W1995141106 cites W1968145455 @default.
- W1995141106 cites W1972546622 @default.
- W1995141106 cites W1997711211 @default.
- W1995141106 cites W2003222517 @default.
- W1995141106 cites W2006081298 @default.
- W1995141106 cites W2010156009 @default.
- W1995141106 cites W2022688037 @default.
- W1995141106 cites W2045520896 @default.
- W1995141106 cites W2048849919 @default.
- W1995141106 cites W2060613375 @default.
- W1995141106 cites W2150527726 @default.
- W1995141106 cites W2324429729 @default.
- W1995141106 cites W2332091730 @default.
- W1995141106 cites W2334053923 @default.
- W1995141106 cites W3137718668 @default.
- W1995141106 cites W3138389000 @default.
- W1995141106 cites W3138767319 @default.
- W1995141106 doi "https://doi.org/10.1016/s0277-5387(00)84676-8" @default.
- W1995141106 hasPublicationYear "1983" @default.
- W1995141106 type Work @default.
- W1995141106 sameAs 1995141106 @default.
- W1995141106 citedByCount "21" @default.
- W1995141106 countsByYear W19951411062016 @default.
- W1995141106 crossrefType "journal-article" @default.
- W1995141106 hasAuthorship W1995141106A5017551100 @default.
- W1995141106 hasAuthorship W1995141106A5026478219 @default.
- W1995141106 hasAuthorship W1995141106A5037217009 @default.
- W1995141106 hasAuthorship W1995141106A5038724542 @default.
- W1995141106 hasConcept C106159729 @default.
- W1995141106 hasConcept C111771559 @default.
- W1995141106 hasConcept C155647269 @default.
- W1995141106 hasConcept C161790260 @default.
- W1995141106 hasConcept C162324750 @default.
- W1995141106 hasConcept C178790620 @default.
- W1995141106 hasConcept C179104552 @default.
- W1995141106 hasConcept C185592680 @default.
- W1995141106 hasConcept C2776568683 @default.
- W1995141106 hasConcept C2777716191 @default.
- W1995141106 hasConcept C2780263894 @default.
- W1995141106 hasConcept C2781213060 @default.
- W1995141106 hasConcept C2993252241 @default.
- W1995141106 hasConcept C515602321 @default.
- W1995141106 hasConcept C71240020 @default.
- W1995141106 hasConcept C8010536 @default.
- W1995141106 hasConceptScore W1995141106C106159729 @default.
- W1995141106 hasConceptScore W1995141106C111771559 @default.
- W1995141106 hasConceptScore W1995141106C155647269 @default.
- W1995141106 hasConceptScore W1995141106C161790260 @default.
- W1995141106 hasConceptScore W1995141106C162324750 @default.
- W1995141106 hasConceptScore W1995141106C178790620 @default.
- W1995141106 hasConceptScore W1995141106C179104552 @default.
- W1995141106 hasConceptScore W1995141106C185592680 @default.
- W1995141106 hasConceptScore W1995141106C2776568683 @default.
- W1995141106 hasConceptScore W1995141106C2777716191 @default.
- W1995141106 hasConceptScore W1995141106C2780263894 @default.
- W1995141106 hasConceptScore W1995141106C2781213060 @default.
- W1995141106 hasConceptScore W1995141106C2993252241 @default.
- W1995141106 hasConceptScore W1995141106C515602321 @default.
- W1995141106 hasConceptScore W1995141106C71240020 @default.
- W1995141106 hasConceptScore W1995141106C8010536 @default.
- W1995141106 hasIssue "2" @default.
- W1995141106 hasLocation W19951411061 @default.
- W1995141106 hasOpenAccess W1995141106 @default.
- W1995141106 hasPrimaryLocation W19951411061 @default.
- W1995141106 hasRelatedWork W2003081455 @default.
- W1995141106 hasRelatedWork W2019646321 @default.
- W1995141106 hasRelatedWork W2041000167 @default.
- W1995141106 hasRelatedWork W2045060966 @default.
- W1995141106 hasRelatedWork W2066718496 @default.
- W1995141106 hasRelatedWork W2068382987 @default.
- W1995141106 hasRelatedWork W2330835763 @default.
- W1995141106 hasRelatedWork W2951014666 @default.
- W1995141106 hasRelatedWork W2951269336 @default.
- W1995141106 hasRelatedWork W1629764367 @default.
- W1995141106 hasVolume "2" @default.
- W1995141106 isParatext "false" @default.
- W1995141106 isRetracted "false" @default.
- W1995141106 magId "1995141106" @default.
- W1995141106 workType "article" @default.