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- W1995180908 abstract "New palladium(II) complexes (2), bearing NHC/TPPTS ligands, (NHC = benzimidazol-2-ylidene; TPPTS = triphenylphosphine-3,3′,3″-trisulfonic acid trisodium salt) have been prepared and characterized by elemental analyses and spectroscopic methods. Their ability to catalyze the Suzuki–Miyaura reaction in neat water has been studied at 100 °C. Very high activities have been observed in the coupling of phenylboronic acid with aryl chlorides in the presence of 1% of the catalyst. We have compared the electronic properties of cis-[PdBr2(NHC)(TPPTS)] with the related complexes, [PdX2(NHC)]2 and [trans-PdBr2(NHC)(pdca)] (pdca = pyridine-2,6-dicarboxyic acid) (3) via three different techniques: cyclic voltammetry, thermogravimetric analysis and 13C NMR spectroscopy." @default.
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- W1995180908 date "2011-09-01" @default.
- W1995180908 modified "2023-10-14" @default.
- W1995180908 title "Water-soluble cis-[(NHC)PdBr2(TPPTS)] catalysts and their applications in Suzuki–Miyaura coupling of aryl chlorides" @default.
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- W1995180908 doi "https://doi.org/10.1016/j.molcata.2011.08.008" @default.
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