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- W1995192135 abstract "The composition and thickness of thin iron oxide films on polycrystalline pure iron were evaluated from Fe 2p spectra as measured by x-ray photoelectron spectroscopy. To this end the experimental spectra were reconstructed from reference spectra of the constituents Fe 0 , Fe 2+ and Fe 3+ . The background contributions in the spectra owing to inelastic scattering of signal electrons were calculated from the depth distributions of these constituents and their reference spectra. In the reconstruction procedure the film thickness and the concentrations of Fe 2+ and Fe 3+ in the oxide film were used as fit parameters The values obtained for the oxide film tbickness were compared with thickness values determined from the intensity of the corresponding O 1s spectra and with thickness values resulting from ellipsometric analysis. The sensitivity of the reconstruction procedure witb regard to film thickness and film composition was tested. © 1998 John Wiley & Sons, Ltd." @default.
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- W1995192135 date "1998-10-01" @default.
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- W1995192135 title "Quantitative analysis of overlapping XPS peaks by spectrum reconstruction: determination of the thickness and composition of thin iron oxide films" @default.
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- W1995192135 doi "https://doi.org/10.1002/(sici)1096-9918(199810)26:11<773::aid-sia419>3.0.co;2-#" @default.
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