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- W1995196664 abstract "Several mixed-ligand complexes of the composition [CuX(trans-dppen)(L)] (X = Br, I) have been prepared by treatment of copper(I) halide with equimolar amounts of trans-1,2-bis(diphenylphosphino)ethene (trans-dppen) in acetonitrile followed by the addition of a methanolic solution of one equivalent of a heterocyclic thione (L). The novel complex compounds have been characterized by 1H NMR and IR spectroscopy as well as by elemental analyses and melting points. The X-ray structures of two representative examples, namely the pyrimidine-2-thione complexes of copper(I) bromide and iodide confirm that the compounds are dimers of type [CuX(μ2-trans-dppen)(L)]2 containing two tetrahedral coordination units joined by two diphosphine bridges." @default.
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- W1995196664 date "2005-01-01" @default.
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- W1995196664 title "Linking thione-ligated copper(I) centres with trans-1,2-bis(diphenylphosphino)ethene (trans-dppen): crystal structures of the pyrimidine-2-thione derivatives [CuBr(μ2-trans-dppen)(pymtH)]2 and [CuI(μ2-trans-dppen)(pymtH)]2" @default.
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- W1995196664 doi "https://doi.org/10.1016/j.poly.2004.11.015" @default.
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