Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995202721> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W1995202721 endingPage "5376" @default.
- W1995202721 startingPage "5372" @default.
- W1995202721 abstract "N,N-di-iso-propylcarbamato derivatives of boron(III) have been synthesized from di-iso-propylamine and boron trichloride in the presence of carbon dioxide. With a large excess of amine, a single boron product was obtained, [NH2iPr2][B(O2CNiPr2)4], 1, while with a lower excess a mixture of 1 and of the dinuclear derivative [B2(O2CNiPr2)6], 2, was produced. By heating in vacuo at 60 °C, solid 1 slowly converted to 2. The transformation was reversible, 2 giving 1 back with di-iso-propylamine under carbon dioxide at atmospheric pressure. The molecular structure of both compounds was established by X-ray diffraction methods. Compound 1 is constituted by ion-pairs where the ammonium cation is hydrogen-bonded to the mononuclear anion. Compound 2 is a dinuclear species with two bridging carbamato ligands. In both derivatives, boron shows tetrahedral coordination. As IR- and 1H NMR spectra of the two species are well differentiated, it is possible to monitor the interconversion of 1 and 2 by both spectroscopic methods." @default.
- W1995202721 created "2016-06-24" @default.
- W1995202721 creator A5005009184 @default.
- W1995202721 creator A5062096538 @default.
- W1995202721 creator A5070296521 @default.
- W1995202721 creator A5082986402 @default.
- W1995202721 date "2008-05-20" @default.
- W1995202721 modified "2023-10-14" @default.
- W1995202721 title "<i>N</i>,<i>N</i>-Di-iso-propylcarbamato Complexes of Boron" @default.
- W1995202721 cites W1539796472 @default.
- W1995202721 cites W1966781526 @default.
- W1995202721 cites W1973572177 @default.
- W1995202721 cites W1980349819 @default.
- W1995202721 cites W2001583134 @default.
- W1995202721 cites W2019660790 @default.
- W1995202721 cites W2039631450 @default.
- W1995202721 cites W2040399634 @default.
- W1995202721 cites W2044790197 @default.
- W1995202721 cites W2051646263 @default.
- W1995202721 cites W2063334178 @default.
- W1995202721 cites W2065341624 @default.
- W1995202721 cites W2073591725 @default.
- W1995202721 cites W2087785329 @default.
- W1995202721 cites W2097883804 @default.
- W1995202721 cites W2131428635 @default.
- W1995202721 cites W2163194823 @default.
- W1995202721 cites W2167590372 @default.
- W1995202721 cites W2237098132 @default.
- W1995202721 cites W2950320209 @default.
- W1995202721 cites W4377431151 @default.
- W1995202721 doi "https://doi.org/10.1021/ic7024523" @default.
- W1995202721 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18489085" @default.
- W1995202721 hasPublicationYear "2008" @default.
- W1995202721 type Work @default.
- W1995202721 sameAs 1995202721 @default.
- W1995202721 citedByCount "10" @default.
- W1995202721 countsByYear W19952027212014 @default.
- W1995202721 countsByYear W19952027212015 @default.
- W1995202721 countsByYear W19952027212020 @default.
- W1995202721 countsByYear W19952027212023 @default.
- W1995202721 crossrefType "journal-article" @default.
- W1995202721 hasAuthorship W1995202721A5005009184 @default.
- W1995202721 hasAuthorship W1995202721A5062096538 @default.
- W1995202721 hasAuthorship W1995202721A5070296521 @default.
- W1995202721 hasAuthorship W1995202721A5082986402 @default.
- W1995202721 hasConcept C106159729 @default.
- W1995202721 hasConcept C111771559 @default.
- W1995202721 hasConcept C131779359 @default.
- W1995202721 hasConcept C145148216 @default.
- W1995202721 hasConcept C147789679 @default.
- W1995202721 hasConcept C153642686 @default.
- W1995202721 hasConcept C155647269 @default.
- W1995202721 hasConcept C162324750 @default.
- W1995202721 hasConcept C178790620 @default.
- W1995202721 hasConcept C179104552 @default.
- W1995202721 hasConcept C185592680 @default.
- W1995202721 hasConcept C2778678469 @default.
- W1995202721 hasConcept C2780850051 @default.
- W1995202721 hasConcept C501308230 @default.
- W1995202721 hasConcept C8010536 @default.
- W1995202721 hasConceptScore W1995202721C106159729 @default.
- W1995202721 hasConceptScore W1995202721C111771559 @default.
- W1995202721 hasConceptScore W1995202721C131779359 @default.
- W1995202721 hasConceptScore W1995202721C145148216 @default.
- W1995202721 hasConceptScore W1995202721C147789679 @default.
- W1995202721 hasConceptScore W1995202721C153642686 @default.
- W1995202721 hasConceptScore W1995202721C155647269 @default.
- W1995202721 hasConceptScore W1995202721C162324750 @default.
- W1995202721 hasConceptScore W1995202721C178790620 @default.
- W1995202721 hasConceptScore W1995202721C179104552 @default.
- W1995202721 hasConceptScore W1995202721C185592680 @default.
- W1995202721 hasConceptScore W1995202721C2778678469 @default.
- W1995202721 hasConceptScore W1995202721C2780850051 @default.
- W1995202721 hasConceptScore W1995202721C501308230 @default.
- W1995202721 hasConceptScore W1995202721C8010536 @default.
- W1995202721 hasIssue "12" @default.
- W1995202721 hasLocation W19952027211 @default.
- W1995202721 hasLocation W19952027212 @default.
- W1995202721 hasOpenAccess W1995202721 @default.
- W1995202721 hasPrimaryLocation W19952027211 @default.
- W1995202721 hasRelatedWork W1965047602 @default.
- W1995202721 hasRelatedWork W2021474564 @default.
- W1995202721 hasRelatedWork W2022074736 @default.
- W1995202721 hasRelatedWork W2043406204 @default.
- W1995202721 hasRelatedWork W2050655304 @default.
- W1995202721 hasRelatedWork W2068572445 @default.
- W1995202721 hasRelatedWork W2072447290 @default.
- W1995202721 hasRelatedWork W2079233114 @default.
- W1995202721 hasRelatedWork W2083234939 @default.
- W1995202721 hasRelatedWork W2085102422 @default.
- W1995202721 hasVolume "47" @default.
- W1995202721 isParatext "false" @default.
- W1995202721 isRetracted "false" @default.
- W1995202721 magId "1995202721" @default.
- W1995202721 workType "article" @default.