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- W1995290003 abstract "Adsorption and reaction of ethylene on clean and H-presaturated Rh(100) have been investigated using HREELS. Adsorption of ethylene on H-presaturated Rh(100) surface at 110 K leads to a π-bonded state, as indicated by a πσ parameter of 0.39 equivalent to that of Zeise's salt. The formation of an ethyl intermediate from the π-bonded ethylene by insertion of preadsorbed H atom already takes place even at 110 K, leading to the evolution of ethane below 200 K. Upon heating, CC bond breakage is promoted on the H-preadsorbed surface, where the strength of metal to H in the adsorbed ethylene is considered to be reduced by preadsorbed hydrogen." @default.
- W1995290003 created "2016-06-24" @default.
- W1995290003 creator A5079048008 @default.
- W1995290003 date "2000-05-01" @default.
- W1995290003 modified "2023-10-03" @default.
- W1995290003 title "Adsorption and reaction of ethylene and hydrogen on Rh(100) surface" @default.
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- W1995290003 doi "https://doi.org/10.1016/s0039-6028(00)00134-5" @default.
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