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- W1995290168 abstract "The flexible alkyl ether functionalized metal–organic framework [Zn2(BME-bdc)2(dabco)]n (BME-bdc = 2,5-bis(2-methoxyethoxy)-1,4-benzenedicarboxylate, dabco = 1,4-diazabicyclo[2.2.2]octane) shows remarkable structural changes upon selective adsorption of CO2 as determined by in situ X-ray diffraction at 195 K. Upon accommodation of carbon dioxide [Zn2(BME-bdc)2(dabco)]n transfers from a narrow pore form to an open pore form, which exhibits a much higher unit cell volume. Due to the slow adsorption kinetics an unexpected metastable intermediate form could be identified." @default.
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- W1995290168 date "2011-01-01" @default.
- W1995290168 modified "2023-09-28" @default.
- W1995290168 title "Multiple phase-transitions upon selective CO2 adsorption in an alkyl ether functionalized metal–organic framework—an in situ X-ray diffraction study" @default.
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- W1995290168 doi "https://doi.org/10.1039/c1ce05446e" @default.
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