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• W1995306870 abstract "Abstract Eight lower-symmetry ordered derivatives of the wurtzite type and an additional six related dipolar tetrahedral structure types were observed. All these structures are based on hexagonal closest packing of anions. Their mutual symmetry relationships can be summarized in a Barnighausen diagram. Dipolar tetrahedral structures are characterized by centrosymmetric space groups, thus resulting in a dipolar distribution of the coordination tetrahedra. Dipolar tetrahedral structures often exhibit disorder and random statistical occupations and several good ionic conductors are found among them. The wurtzite-type derivatives are characterized by polar space groups and all coordination tetrahedra in them are pointing in the same direction. Some simple, geometrically possible wurtzite derivatives have never been observed. Their absence can be rationalized on the basis of a poor geometrical fit between tetrahedral chains as demonstrated by computer simulations of their hypothetical structures. The ratio ϵ (quotient of the thickness of one hexagonal layer in [001] over one measure of the mean diameter of one atom within this layer) is useful for ordering the wurtzite derivatives on the basis of their chemical composition, since ϵ increases from the oxides, over the nitrides to the sulfides. The ϵ ratio also distinguishes clearly between the oxidic wurtzite types (0.79) and the tetrahedral rutile types of β-BeO derivatives (0.86), while the dipolar tetrahedral types have ϵ values around 0.82, that is, close to the value expected for hexagonal closest packing." @default.
• W1995306870 created "2016-06-24" @default.
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• W1995306870 date "1982-05-01" @default.
• W1995306870 modified "2023-09-25" @default.
• W1995306870 title "Observed wurtzite derivatives and related dipolar tetrahedral structures" @default.
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• W1995306870 doi "https://doi.org/10.1016/0022-4596(82)90008-1" @default.
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