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- W1995342283 abstract "Vanadium-containing polyoxometalates (POM) were synthesized under acidic conditions and characterized by XRD, FT-IR, 51V MAS-NMR, EXAFS-XANES and SEM. POM crystals were successfully grown under acidic atmosphere, thus forming a self-assembled structure. This self-organized structure was constituted by cubic crystals having between 20 and 80 μm in size. Both 51V MAS-NMR, EXAFS-XANES and PM6 calculations suggest that non-covalent interactions, such as hydrogen bonding, or shared vanadium atoms of non-complete coordination are the driving force of the self-assembly process." @default.
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- W1995342283 date "2010-11-01" @default.
- W1995342283 modified "2023-09-30" @default.
- W1995342283 title "Synthesis of Keggin-type polyoxometalate crystals" @default.
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- W1995342283 doi "https://doi.org/10.1016/j.solidstatesciences.2010.01.022" @default.
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