FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995380050> ?p ?o ?g. }

• W1995380050 endingPage "2611" @default.
• W1995380050 startingPage "2605" @default.
• W1995380050 abstract "Reactions of trialkylalanes AlR3 (R = Me, Et, tBu) and triorganylbismuthanes BiR′3 (R′ = iPr, SiMe3) were performed and the products investigated both in solution and in the solid state. Et3Al−Bi(SiMe3)3 (2), tBu3Al−Bi(SiMe3)3 (3), and tBu3Al−Bi(iPr)3 (6) are stable Lewis acid−base adducts in pure form while only 3 and 6 are adducts in solution. Their dissociation enthalpies, as determined by temperature-dependent NMR spectroscopy, were estimated to 6.3 (3) and 6.9 kcal/mol (6). In contrast, Me3Al−Bi(SiMe3)3 (1), Et3Al−Bi(SiMe3)3 (2), Me3Al−Bi(iPr)3 (4), and Et3Al−Bi(iPr)3 (5) are fully dissociated in solution. Compounds 1−6 were characterized by multinuclear NMR spectroscopy (1H, 13C), mass spectrometry, and elemental analysis. In addition, the crystal structures of 2 and 6 were determined by single-crystal X-ray diffraction. Compounds 2 and 6 are the first structurally characterized alane−triorganylbismuthane Lewis acid−base adducts." @default.
• W1995380050 created "2016-06-24" @default.
• W1995380050 creator A5004351252 @default.
• W1995380050 creator A5043452704 @default.
• W1995380050 creator A5063916861 @default.
• W1995380050 date "2001-09-01" @default.
• W1995380050 modified "2023-10-18" @default.
• W1995380050 title "Synthesis, X-ray Crystal Structure, and Stability of Novel Trialkylalane−Triorganylbismuthane Adducts" @default.
• W1995380050 cites W1541102534 @default.
• W1995380050 cites W1968449908 @default.
• W1995380050 cites W1973152354 @default.
• W1995380050 cites W1986768929 @default.
• W1995380050 cites W1989672901 @default.
• W1995380050 cites W1991139059 @default.
• W1995380050 cites W1994634720 @default.
• W1995380050 cites W2000101737 @default.
• W1995380050 cites W2001153133 @default.
• W1995380050 cites W2004301363 @default.
• W1995380050 cites W2008507011 @default.
• W1995380050 cites W2010299390 @default.
• W1995380050 cites W2012354329 @default.
• W1995380050 cites W2020698069 @default.
• W1995380050 cites W2034887381 @default.
• W1995380050 cites W2061826733 @default.
• W1995380050 cites W2069670920 @default.
• W1995380050 cites W2070550667 @default.
• W1995380050 cites W2080961627 @default.
• W1995380050 cites W2086941148 @default.
• W1995380050 cites W2097437154 @default.
• W1995380050 cites W2111291991 @default.
• W1995380050 cites W2124047025 @default.
• W1995380050 cites W2141788184 @default.
• W1995380050 cites W2148066840 @default.
• W1995380050 cites W2949239029 @default.
• W1995380050 cites W3137881638 @default.
• W1995380050 doi "https://doi.org/10.1002/1099-0682(200109)2001:10<2605::aid-ejic2605>3.0.co;2-x" @default.
• W1995380050 hasPublicationYear "2001" @default.
• W1995380050 type Work @default.
• W1995380050 sameAs 1995380050 @default.
• W1995380050 citedByCount "30" @default.
• W1995380050 countsByYear W19953800502012 @default.
• W1995380050 countsByYear W19953800502013 @default.
• W1995380050 countsByYear W19953800502014 @default.
• W1995380050 countsByYear W19953800502015 @default.
• W1995380050 countsByYear W19953800502016 @default.
• W1995380050 countsByYear W19953800502018 @default.
• W1995380050 countsByYear W19953800502021 @default.
• W1995380050 crossrefType "journal-article" @default.
• W1995380050 hasAuthorship W1995380050A5004351252 @default.
• W1995380050 hasAuthorship W1995380050A5043452704 @default.
• W1995380050 hasAuthorship W1995380050A5063916861 @default.
• W1995380050 hasConcept C102931765 @default.
• W1995380050 hasConcept C108204754 @default.
• W1995380050 hasConcept C115624301 @default.
• W1995380050 hasConcept C121332964 @default.
• W1995380050 hasConcept C147789679 @default.
• W1995380050 hasConcept C155647269 @default.
• W1995380050 hasConcept C161790260 @default.
• W1995380050 hasConcept C162356407 @default.
• W1995380050 hasConcept C163638829 @default.
• W1995380050 hasConcept C178790620 @default.
• W1995380050 hasConcept C179104552 @default.
• W1995380050 hasConcept C185592680 @default.
• W1995380050 hasConcept C32891209 @default.
• W1995380050 hasConcept C43617362 @default.
• W1995380050 hasConcept C62520636 @default.
• W1995380050 hasConcept C64885871 @default.
• W1995380050 hasConcept C66974803 @default.
• W1995380050 hasConcept C71240020 @default.
• W1995380050 hasConcept C8010536 @default.
• W1995380050 hasConceptScore W1995380050C102931765 @default.
• W1995380050 hasConceptScore W1995380050C108204754 @default.
• W1995380050 hasConceptScore W1995380050C115624301 @default.
• W1995380050 hasConceptScore W1995380050C121332964 @default.
• W1995380050 hasConceptScore W1995380050C147789679 @default.
• W1995380050 hasConceptScore W1995380050C155647269 @default.
• W1995380050 hasConceptScore W1995380050C161790260 @default.
• W1995380050 hasConceptScore W1995380050C162356407 @default.
• W1995380050 hasConceptScore W1995380050C163638829 @default.
• W1995380050 hasConceptScore W1995380050C178790620 @default.
• W1995380050 hasConceptScore W1995380050C179104552 @default.
• W1995380050 hasConceptScore W1995380050C185592680 @default.
• W1995380050 hasConceptScore W1995380050C32891209 @default.
• W1995380050 hasConceptScore W1995380050C43617362 @default.
• W1995380050 hasConceptScore W1995380050C62520636 @default.
• W1995380050 hasConceptScore W1995380050C64885871 @default.
• W1995380050 hasConceptScore W1995380050C66974803 @default.
• W1995380050 hasConceptScore W1995380050C71240020 @default.
• W1995380050 hasConceptScore W1995380050C8010536 @default.
• W1995380050 hasIssue "10" @default.
• W1995380050 hasLocation W19953800501 @default.
• W1995380050 hasOpenAccess W1995380050 @default.
• W1995380050 hasPrimaryLocation W19953800501 @default.
• W1995380050 hasRelatedWork W1575926188 @default.
• W1995380050 hasRelatedWork W1989672901 @default.
• W1995380050 hasRelatedWork W2026948689 @default.
• W1995380050 hasRelatedWork W2038804434 @default.
• W1995380050 hasRelatedWork W2047991101 @default.

• next