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• W1995389623 abstract "In order to rule out any possible ‘chelat’ iron-proton interaction which could be responsible for the dramatic changes observed in the Fe 1 /Fe redox potential on proton addition in a series of N-substituted aminomethyl ferrocenes ( 4a-d ), we report the results of electrochemical titration experiments with strong acids on the free amines in protic and aprotic solvents and the X-ray diffraction structure of (ferrocenyl-methyl) propylammonium p -toluenesulfonate, [ 4a H[OTs]. Crystals of [ 4a H][OTs] are orthorhombic, space group P 2 1 2 1 2 1 , with a=11.919(2), b=21.313(3), c=8.246(2) A ̊ , Z=4 . The conformation of the FcCH 2 NH 2 C 3 H 7 cation, which prevents any intramolecular iron-proton interaction, seems imposed by the intermolecular NH⋯O hydrogen bonds that the amino H atoms form with oxygen atoms from p -toluenesulfonate anions." @default.
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• W1995389623 date "1998-01-01" @default.
• W1995389623 modified "2023-09-24" @default.
• W1995389623 title "Crystal and molecular structure of protonated (N-propyl)-aminomethyl ferrocene, a proton-sensitive redox-responsive fragment" @default.
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• W1995389623 doi "https://doi.org/10.1016/s0020-1693(97)05577-1" @default.
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