FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995404612> ?p ?o ?g. }

• W1995404612 endingPage "186" @default.
• W1995404612 startingPage "169" @default.
• W1995404612 abstract "Anionic clays with hydrotalcite-type (HT) structures (mixed hydroxides containing exchangeable anions) have many interesting industrial applications; in particular, they may be useful precursors of multicomponent catalysts such as, for example, Ni/Al catalysts for steam reforming of methane and higher paraffins. The structure and the synthesis of HT anionic clays are examined in order to identify the key factors involved in the preparation of pure compounds, the homogeneity of which can be verified by various techniques (XRD, EXAFS, 27Al NMR and TG analysis). TG and DSC analyses of HT precipitates show that their decomposition involves an initial loss of interlayer water followed by the elimination of hydroxide and carbonate ions, with some differences related to the composition and crystallinity of the samples. The aluminum-containing samples obtained by thermal decomposition exhibit high surface area and stability, and are characterized by the small size and the low reducibility of NiO particles. For Ni/Al and Ni/Cr samples, the formation of spinel phases has a negative effect, giving rise to remarkable increases in both NiO crystal size and reducibility, while for Ni/Mg/Al samples this increase of reducibility is not necessarily observed always as a function of the formation of NiO/MgO solid solutions. A model for Ni/Al mixed oxides obtained from HT anionic clays is proposed involving the formation of NiO and Ni-doped alumina phases, which strongly interact with a spinel-type phase present at their interface. This phase is thought to be responsible for the thermal stability and low reducibility of the NiO particles. The validity of this model is discussed as a function of the different HT anionic clay compositions examined and of the phases formed at different calcination temperatures." @default.
• W1995404612 created "2016-06-24" @default.
• W1995404612 creator A5036490820 @default.
• W1995404612 creator A5046172547 @default.
• W1995404612 creator A5049356721 @default.
• W1995404612 creator A5053782254 @default.
• W1995404612 creator A5062950502 @default.
• W1995404612 creator A5091079953 @default.
• W1995404612 date "1993-08-01" @default.
• W1995404612 modified "2023-10-16" @default.
• W1995404612 title "Synthesis and thermal reactivity of nickel-containing anionic clays" @default.
• W1995404612 cites W1535702013 @default.
• W1995404612 cites W1967248933 @default.
• W1995404612 cites W1981917819 @default.
• W1995404612 cites W1987507786 @default.
• W1995404612 cites W1987720467 @default.
• W1995404612 cites W1991073290 @default.
• W1995404612 cites W1996280739 @default.
• W1995404612 cites W1996941785 @default.
• W1995404612 cites W2000462517 @default.
• W1995404612 cites W2013845600 @default.
• W1995404612 cites W2019237191 @default.
• W1995404612 cites W2028196186 @default.
• W1995404612 cites W2028877955 @default.
• W1995404612 cites W2042095755 @default.
• W1995404612 cites W2066206239 @default.
• W1995404612 cites W2067816908 @default.
• W1995404612 cites W2072465370 @default.
• W1995404612 cites W2075868131 @default.
• W1995404612 cites W2077295376 @default.
• W1995404612 cites W2083595698 @default.
• W1995404612 cites W2086106931 @default.
• W1995404612 cites W2086254568 @default.
• W1995404612 cites W2087548647 @default.
• W1995404612 cites W2128160306 @default.
• W1995404612 cites W2167590372 @default.
• W1995404612 doi "https://doi.org/10.1016/0169-1317(93)90035-y" @default.
• W1995404612 hasPublicationYear "1993" @default.
• W1995404612 type Work @default.
• W1995404612 sameAs 1995404612 @default.
• W1995404612 citedByCount "62" @default.
• W1995404612 countsByYear W19954046122012 @default.
• W1995404612 countsByYear W19954046122013 @default.
• W1995404612 countsByYear W19954046122014 @default.
• W1995404612 countsByYear W19954046122015 @default.
• W1995404612 countsByYear W19954046122016 @default.
• W1995404612 countsByYear W19954046122017 @default.
• W1995404612 countsByYear W19954046122018 @default.
• W1995404612 countsByYear W19954046122019 @default.
• W1995404612 countsByYear W19954046122020 @default.
• W1995404612 countsByYear W19954046122021 @default.
• W1995404612 countsByYear W19954046122022 @default.
• W1995404612 countsByYear W19954046122023 @default.
• W1995404612 crossrefType "journal-article" @default.
• W1995404612 hasAuthorship W1995404612A5036490820 @default.
• W1995404612 hasAuthorship W1995404612A5046172547 @default.
• W1995404612 hasAuthorship W1995404612A5049356721 @default.
• W1995404612 hasAuthorship W1995404612A5053782254 @default.
• W1995404612 hasAuthorship W1995404612A5062950502 @default.
• W1995404612 hasAuthorship W1995404612A5091079953 @default.
• W1995404612 hasConcept C127413603 @default.
• W1995404612 hasConcept C160434732 @default.
• W1995404612 hasConcept C161790260 @default.
• W1995404612 hasConcept C178790620 @default.
• W1995404612 hasConcept C179104552 @default.
• W1995404612 hasConcept C185592680 @default.
• W1995404612 hasConcept C191897082 @default.
• W1995404612 hasConcept C192562407 @default.
• W1995404612 hasConcept C2775896084 @default.
• W1995404612 hasConcept C2776230739 @default.
• W1995404612 hasConcept C2778002958 @default.
• W1995404612 hasConcept C42360764 @default.
• W1995404612 hasConcept C46275449 @default.
• W1995404612 hasConcept C504270822 @default.
• W1995404612 hasConcept C59061564 @default.
• W1995404612 hasConcept C64792281 @default.
• W1995404612 hasConcept C74575197 @default.
• W1995404612 hasConcept C8010536 @default.
• W1995404612 hasConceptScore W1995404612C127413603 @default.
• W1995404612 hasConceptScore W1995404612C160434732 @default.
• W1995404612 hasConceptScore W1995404612C161790260 @default.
• W1995404612 hasConceptScore W1995404612C178790620 @default.
• W1995404612 hasConceptScore W1995404612C179104552 @default.
• W1995404612 hasConceptScore W1995404612C185592680 @default.
• W1995404612 hasConceptScore W1995404612C191897082 @default.
• W1995404612 hasConceptScore W1995404612C192562407 @default.
• W1995404612 hasConceptScore W1995404612C2775896084 @default.
• W1995404612 hasConceptScore W1995404612C2776230739 @default.
• W1995404612 hasConceptScore W1995404612C2778002958 @default.
• W1995404612 hasConceptScore W1995404612C42360764 @default.
• W1995404612 hasConceptScore W1995404612C46275449 @default.
• W1995404612 hasConceptScore W1995404612C504270822 @default.
• W1995404612 hasConceptScore W1995404612C59061564 @default.
• W1995404612 hasConceptScore W1995404612C64792281 @default.
• W1995404612 hasConceptScore W1995404612C74575197 @default.
• W1995404612 hasConceptScore W1995404612C8010536 @default.
• W1995404612 hasIssue "2-3" @default.
• W1995404612 hasLocation W19954046121 @default.

• next