Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995418060> ?p ?o ?g. }
- W1995418060 endingPage "18287" @default.
- W1995418060 startingPage "18282" @default.
- W1995418060 abstract "We have examined the stereoselectivity of molecular recognition between two molecules of the anesthetic sevoflurane using broadband rotational spectroscopy. The transient axial chirality of sevoflurane is revealed upon the formation of the dimer, as two different diastereoisomers made of either homo- or heterochiral species are detected in a supersonic jet expansion. The conformational assignment was confirmed by the observation of eighteen different isotopologues in natural abundance (all possible (13)C's and two (18)O species of the homochiral form). The two clusters are formed in practically equal proportions (1.1 : 1), probably due to their similar hydrogen bonding topologies. In both clusters the complex is stabilized by a primary C-H···O hydrogen bond, assisted by weak C-HF interactions. This intermolecular binding regime is characterized by a mixture of electrostatic and dispersive interactions, midway between classical hydrogen bonds and van der Waals clusters." @default.
- W1995418060 created "2016-06-24" @default.
- W1995418060 creator A5006290698 @default.
- W1995418060 creator A5015084638 @default.
- W1995418060 creator A5041133025 @default.
- W1995418060 creator A5073862765 @default.
- W1995418060 creator A5074818598 @default.
- W1995418060 creator A5079330861 @default.
- W1995418060 creator A5082124503 @default.
- W1995418060 creator A5083286476 @default.
- W1995418060 date "2015-01-01" @default.
- W1995418060 modified "2023-10-18" @default.
- W1995418060 title "Chiral recognition and atropisomerism in the sevoflurane dimer" @default.
- W1995418060 cites W1528130557 @default.
- W1995418060 cites W1964277385 @default.
- W1995418060 cites W1974345759 @default.
- W1995418060 cites W1975605937 @default.
- W1995418060 cites W1986864663 @default.
- W1995418060 cites W1990235385 @default.
- W1995418060 cites W1991454272 @default.
- W1995418060 cites W2007698700 @default.
- W1995418060 cites W2021433262 @default.
- W1995418060 cites W2025204525 @default.
- W1995418060 cites W2039735251 @default.
- W1995418060 cites W2047874202 @default.
- W1995418060 cites W2049215393 @default.
- W1995418060 cites W2049692419 @default.
- W1995418060 cites W2050890227 @default.
- W1995418060 cites W2058351610 @default.
- W1995418060 cites W2069723789 @default.
- W1995418060 cites W2080819782 @default.
- W1995418060 cites W2094414406 @default.
- W1995418060 cites W2095465647 @default.
- W1995418060 cites W2096778397 @default.
- W1995418060 cites W2100208256 @default.
- W1995418060 cites W2110260741 @default.
- W1995418060 cites W2111705896 @default.
- W1995418060 cites W2120552054 @default.
- W1995418060 cites W2125282370 @default.
- W1995418060 cites W2132109560 @default.
- W1995418060 cites W2144239168 @default.
- W1995418060 cites W2147304506 @default.
- W1995418060 cites W2148758256 @default.
- W1995418060 cites W2474436045 @default.
- W1995418060 cites W4236703540 @default.
- W1995418060 doi "https://doi.org/10.1039/c5cp01025j" @default.
- W1995418060 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25959977" @default.
- W1995418060 hasPublicationYear "2015" @default.
- W1995418060 type Work @default.
- W1995418060 sameAs 1995418060 @default.
- W1995418060 citedByCount "23" @default.
- W1995418060 countsByYear W19954180602016 @default.
- W1995418060 countsByYear W19954180602017 @default.
- W1995418060 countsByYear W19954180602018 @default.
- W1995418060 countsByYear W19954180602019 @default.
- W1995418060 countsByYear W19954180602020 @default.
- W1995418060 countsByYear W19954180602021 @default.
- W1995418060 countsByYear W19954180602022 @default.
- W1995418060 countsByYear W19954180602023 @default.
- W1995418060 crossrefType "journal-article" @default.
- W1995418060 hasAuthorship W1995418060A5006290698 @default.
- W1995418060 hasAuthorship W1995418060A5015084638 @default.
- W1995418060 hasAuthorship W1995418060A5041133025 @default.
- W1995418060 hasAuthorship W1995418060A5073862765 @default.
- W1995418060 hasAuthorship W1995418060A5074818598 @default.
- W1995418060 hasAuthorship W1995418060A5079330861 @default.
- W1995418060 hasAuthorship W1995418060A5082124503 @default.
- W1995418060 hasAuthorship W1995418060A5083286476 @default.
- W1995418060 hasConcept C112887158 @default.
- W1995418060 hasConcept C121332964 @default.
- W1995418060 hasConcept C124668440 @default.
- W1995418060 hasConcept C126061179 @default.
- W1995418060 hasConcept C138716334 @default.
- W1995418060 hasConcept C13934619 @default.
- W1995418060 hasConcept C147597530 @default.
- W1995418060 hasConcept C166950319 @default.
- W1995418060 hasConcept C178790620 @default.
- W1995418060 hasConcept C185592680 @default.
- W1995418060 hasConcept C20621625 @default.
- W1995418060 hasConcept C2779546866 @default.
- W1995418060 hasConcept C32909587 @default.
- W1995418060 hasConcept C52703039 @default.
- W1995418060 hasConcept C62520636 @default.
- W1995418060 hasConcept C71240020 @default.
- W1995418060 hasConcept C7602139 @default.
- W1995418060 hasConcept C8010536 @default.
- W1995418060 hasConceptScore W1995418060C112887158 @default.
- W1995418060 hasConceptScore W1995418060C121332964 @default.
- W1995418060 hasConceptScore W1995418060C124668440 @default.
- W1995418060 hasConceptScore W1995418060C126061179 @default.
- W1995418060 hasConceptScore W1995418060C138716334 @default.
- W1995418060 hasConceptScore W1995418060C13934619 @default.
- W1995418060 hasConceptScore W1995418060C147597530 @default.
- W1995418060 hasConceptScore W1995418060C166950319 @default.
- W1995418060 hasConceptScore W1995418060C178790620 @default.
- W1995418060 hasConceptScore W1995418060C185592680 @default.
- W1995418060 hasConceptScore W1995418060C20621625 @default.
- W1995418060 hasConceptScore W1995418060C2779546866 @default.