Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995422901> ?p ?o ?g. }
- W1995422901 endingPage "3555" @default.
- W1995422901 startingPage "3548" @default.
- W1995422901 abstract "We present a direct side-by-side comparison of the interaction of Li atoms and N2 molecules on the atomically stepped Ru(1 0 9) single crystal surface and on the atomically smooth Ru(0 0 1) single crystal surface using infrared reflection absorption spectroscopy (IRAS) and temperature programmed desorption (TPD). At low adsorbate coverages there is spectroscopic evidence for the formation of a Lix(N2)y complex on the Ru(1 0 9) surface, whereas no such complex is observed on the Ru(0 0 1) surface. This complex is due to local interactions between an adsorbed Li atom and N2 adsorbed on the atomic steps of Ru(1 0 9). The short range interaction near the atomic steps is characterized by the development of several highly red-shifted ν(N2) modes in the region of ∼2130 cm−1 in the IR spectra. Adsorbed N2 molecules on both Ru(1 0 9) and Ru(0 0 1) also are influenced by the long range electrostatic field produced by Li adsorbate atoms, causing a red shift in the uncomplexed N2 species, which monotonically increases as the Li coverage in increased. On the Ru(0 0 1) surface, small coverages of N2 influenced by the long range effect of Li are initially chemisorbed parallel to the surface resulting in the absence of infrared activity. In addition we have also found that Li does not cause N–N bond scission on Ru(0 0 1) below 250 K." @default.
- W1995422901 created "2016-06-24" @default.
- W1995422901 creator A5007112043 @default.
- W1995422901 creator A5040150200 @default.
- W1995422901 creator A5077583541 @default.
- W1995422901 date "2007-09-01" @default.
- W1995422901 modified "2023-10-12" @default.
- W1995422901 title "Interaction between chemisorbed N2 and Li promoter atoms: A comparison between the stepped Ru(109) and the atomically smooth Ru(001) surfaces" @default.
- W1995422901 cites W16400372 @default.
- W1995422901 cites W1656038169 @default.
- W1995422901 cites W1972041574 @default.
- W1995422901 cites W1975205877 @default.
- W1995422901 cites W1976129612 @default.
- W1995422901 cites W1987113671 @default.
- W1995422901 cites W1995583547 @default.
- W1995422901 cites W1997419089 @default.
- W1995422901 cites W2002448728 @default.
- W1995422901 cites W2003412026 @default.
- W1995422901 cites W2007026443 @default.
- W1995422901 cites W2010746168 @default.
- W1995422901 cites W2013275620 @default.
- W1995422901 cites W2015782263 @default.
- W1995422901 cites W2017956917 @default.
- W1995422901 cites W2018777375 @default.
- W1995422901 cites W2023413810 @default.
- W1995422901 cites W2028632277 @default.
- W1995422901 cites W2038146686 @default.
- W1995422901 cites W2040710119 @default.
- W1995422901 cites W2046494433 @default.
- W1995422901 cites W2048668098 @default.
- W1995422901 cites W2048697034 @default.
- W1995422901 cites W2068419640 @default.
- W1995422901 cites W2071937688 @default.
- W1995422901 cites W2084144337 @default.
- W1995422901 cites W2105586031 @default.
- W1995422901 cites W2169719272 @default.
- W1995422901 cites W4255566435 @default.
- W1995422901 cites W4361864895 @default.
- W1995422901 doi "https://doi.org/10.1016/j.susc.2007.04.160" @default.
- W1995422901 hasPublicationYear "2007" @default.
- W1995422901 type Work @default.
- W1995422901 sameAs 1995422901 @default.
- W1995422901 citedByCount "6" @default.
- W1995422901 countsByYear W19954229012013 @default.
- W1995422901 crossrefType "journal-article" @default.
- W1995422901 hasAuthorship W1995422901A5007112043 @default.
- W1995422901 hasAuthorship W1995422901A5040150200 @default.
- W1995422901 hasAuthorship W1995422901A5077583541 @default.
- W1995422901 hasConcept C120665830 @default.
- W1995422901 hasConcept C121332964 @default.
- W1995422901 hasConcept C125287762 @default.
- W1995422901 hasConcept C147789679 @default.
- W1995422901 hasConcept C149635348 @default.
- W1995422901 hasConcept C150394285 @default.
- W1995422901 hasConcept C153642686 @default.
- W1995422901 hasConcept C158355884 @default.
- W1995422901 hasConcept C159985019 @default.
- W1995422901 hasConcept C161790260 @default.
- W1995422901 hasConcept C162711632 @default.
- W1995422901 hasConcept C178790620 @default.
- W1995422901 hasConcept C185592680 @default.
- W1995422901 hasConcept C192562407 @default.
- W1995422901 hasConcept C199360897 @default.
- W1995422901 hasConcept C2781285689 @default.
- W1995422901 hasConcept C32909587 @default.
- W1995422901 hasConcept C33790079 @default.
- W1995422901 hasConcept C41008148 @default.
- W1995422901 hasConcept C55493867 @default.
- W1995422901 hasConcept C555196967 @default.
- W1995422901 hasConcept C58312451 @default.
- W1995422901 hasConcept C73922627 @default.
- W1995422901 hasConcept C8010536 @default.
- W1995422901 hasConceptScore W1995422901C120665830 @default.
- W1995422901 hasConceptScore W1995422901C121332964 @default.
- W1995422901 hasConceptScore W1995422901C125287762 @default.
- W1995422901 hasConceptScore W1995422901C147789679 @default.
- W1995422901 hasConceptScore W1995422901C149635348 @default.
- W1995422901 hasConceptScore W1995422901C150394285 @default.
- W1995422901 hasConceptScore W1995422901C153642686 @default.
- W1995422901 hasConceptScore W1995422901C158355884 @default.
- W1995422901 hasConceptScore W1995422901C159985019 @default.
- W1995422901 hasConceptScore W1995422901C161790260 @default.
- W1995422901 hasConceptScore W1995422901C162711632 @default.
- W1995422901 hasConceptScore W1995422901C178790620 @default.
- W1995422901 hasConceptScore W1995422901C185592680 @default.
- W1995422901 hasConceptScore W1995422901C192562407 @default.
- W1995422901 hasConceptScore W1995422901C199360897 @default.
- W1995422901 hasConceptScore W1995422901C2781285689 @default.
- W1995422901 hasConceptScore W1995422901C32909587 @default.
- W1995422901 hasConceptScore W1995422901C33790079 @default.
- W1995422901 hasConceptScore W1995422901C41008148 @default.
- W1995422901 hasConceptScore W1995422901C55493867 @default.
- W1995422901 hasConceptScore W1995422901C555196967 @default.
- W1995422901 hasConceptScore W1995422901C58312451 @default.
- W1995422901 hasConceptScore W1995422901C73922627 @default.
- W1995422901 hasConceptScore W1995422901C8010536 @default.
- W1995422901 hasIssue "17" @default.
- W1995422901 hasLocation W19954229011 @default.