Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995436329> ?p ?o ?g. }
- W1995436329 endingPage "866" @default.
- W1995436329 startingPage "860" @default.
- W1995436329 abstract "Bis(vinyl-Cp)zirconium dichloride (6) undergoes a clean intramolecular photochemically induced [2+2] cycloaddition reaction to yield the cyclobutylene-bridged ansa-zirconocene isomer (7) when irradiated with UV light (HPK 125, Pyrex filter) at ambient conditions. Both the open and the ansa-bridged isomers (6, 7) were characterized by X-ray diffraction. The corresponding bis(2-vinylindenyl)ZrCl2 complex (12) also closes rapidly and completely to the ansa-metallocene (13) upon photolysis. The bis(2-butadienylindenyl)ZrCl2 complex (20) undergoes a formal [4+4] cycloaddition reaction upon photolysis to yield its ansa-metallocene isomer 21, exhibiting an eight-membered carbocyclic bridging unit. The metallocene complexes prepared and characterized in this study give very active ethene polymerization catalysts upon activation with excess methylalumoxane." @default.
- W1995436329 created "2016-06-24" @default.
- W1995436329 creator A5034468058 @default.
- W1995436329 creator A5034807035 @default.
- W1995436329 creator A5039921470 @default.
- W1995436329 creator A5048542589 @default.
- W1995436329 date "2010-01-15" @default.
- W1995436329 modified "2023-10-11" @default.
- W1995436329 title "Functional Group Chemistry at the Group 4 Bent Metallocene Framework: [2+2] Cycloaddition of the Parent Bis(vinyl-Cp/vinyl-Ind)ZrCl<sub>2</sub> Systems" @default.
- W1995436329 cites W1963856393 @default.
- W1995436329 cites W1964936863 @default.
- W1995436329 cites W1970853127 @default.
- W1995436329 cites W1973975789 @default.
- W1995436329 cites W1974844511 @default.
- W1995436329 cites W1974862305 @default.
- W1995436329 cites W1981963295 @default.
- W1995436329 cites W1982679126 @default.
- W1995436329 cites W1989330126 @default.
- W1995436329 cites W1990828610 @default.
- W1995436329 cites W1991834651 @default.
- W1995436329 cites W1992652612 @default.
- W1995436329 cites W1993610879 @default.
- W1995436329 cites W1999407022 @default.
- W1995436329 cites W2002091772 @default.
- W1995436329 cites W2003416822 @default.
- W1995436329 cites W2005232062 @default.
- W1995436329 cites W2007183084 @default.
- W1995436329 cites W2013903428 @default.
- W1995436329 cites W2016467808 @default.
- W1995436329 cites W2022424672 @default.
- W1995436329 cites W2023429264 @default.
- W1995436329 cites W2023605656 @default.
- W1995436329 cites W2028990075 @default.
- W1995436329 cites W2038340466 @default.
- W1995436329 cites W2040089285 @default.
- W1995436329 cites W2040505321 @default.
- W1995436329 cites W2042953778 @default.
- W1995436329 cites W2044580907 @default.
- W1995436329 cites W2048904716 @default.
- W1995436329 cites W2051594970 @default.
- W1995436329 cites W2062424252 @default.
- W1995436329 cites W2074831856 @default.
- W1995436329 cites W2077307621 @default.
- W1995436329 cites W2080910989 @default.
- W1995436329 cites W2107781388 @default.
- W1995436329 cites W2127969108 @default.
- W1995436329 cites W2132897544 @default.
- W1995436329 cites W2133156507 @default.
- W1995436329 cites W2139095501 @default.
- W1995436329 cites W2139193183 @default.
- W1995436329 cites W2139669070 @default.
- W1995436329 cites W2149295256 @default.
- W1995436329 cites W2153387011 @default.
- W1995436329 cites W2153900045 @default.
- W1995436329 cites W2950811333 @default.
- W1995436329 cites W2951456719 @default.
- W1995436329 cites W2953194131 @default.
- W1995436329 cites W4245906240 @default.
- W1995436329 doi "https://doi.org/10.1021/om900939v" @default.
- W1995436329 hasPublicationYear "2010" @default.
- W1995436329 type Work @default.
- W1995436329 sameAs 1995436329 @default.
- W1995436329 citedByCount "9" @default.
- W1995436329 countsByYear W19954363292012 @default.
- W1995436329 countsByYear W19954363292015 @default.
- W1995436329 countsByYear W19954363292016 @default.
- W1995436329 countsByYear W19954363292018 @default.
- W1995436329 countsByYear W19954363292021 @default.
- W1995436329 countsByYear W19954363292022 @default.
- W1995436329 crossrefType "journal-article" @default.
- W1995436329 hasAuthorship W1995436329A5034468058 @default.
- W1995436329 hasAuthorship W1995436329A5034807035 @default.
- W1995436329 hasAuthorship W1995436329A5039921470 @default.
- W1995436329 hasAuthorship W1995436329A5048542589 @default.
- W1995436329 hasConcept C155647269 @default.
- W1995436329 hasConcept C161790260 @default.
- W1995436329 hasConcept C178790620 @default.
- W1995436329 hasConcept C185592680 @default.
- W1995436329 hasConcept C188027245 @default.
- W1995436329 hasConcept C2779664164 @default.
- W1995436329 hasConcept C2780446808 @default.
- W1995436329 hasConcept C44228677 @default.
- W1995436329 hasConcept C521977710 @default.
- W1995436329 hasConcept C534791751 @default.
- W1995436329 hasConcept C75079739 @default.
- W1995436329 hasConcept C75473681 @default.
- W1995436329 hasConceptScore W1995436329C155647269 @default.
- W1995436329 hasConceptScore W1995436329C161790260 @default.
- W1995436329 hasConceptScore W1995436329C178790620 @default.
- W1995436329 hasConceptScore W1995436329C185592680 @default.
- W1995436329 hasConceptScore W1995436329C188027245 @default.
- W1995436329 hasConceptScore W1995436329C2779664164 @default.
- W1995436329 hasConceptScore W1995436329C2780446808 @default.
- W1995436329 hasConceptScore W1995436329C44228677 @default.
- W1995436329 hasConceptScore W1995436329C521977710 @default.
- W1995436329 hasConceptScore W1995436329C534791751 @default.
- W1995436329 hasConceptScore W1995436329C75079739 @default.
- W1995436329 hasConceptScore W1995436329C75473681 @default.