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• W1995437229 endingPage "11177" @default.
• W1995437229 startingPage "11160" @default.
• W1995437229 abstract "Under neutral conditions the reactions between 4-amino-1,2,4-triazole and cyano-substituted benzaldehyde derivatives yield stable hemiaminals. Addition of small amounts of acid catalyst promotes further step of dehydration resulting in formation of Schiff bases. Four new hemiaminals and the corresponding imines have been obtained. The molecular stability of the hemiaminal intermediates results from both the 1,2,4-triazole moiety and electron withdrawing substituents on the phenyl ring, so no further stabilisation by intramolecular interaction is required. Hemiaminal molecules possess stereogenic centres on carbon and nitrogen atoms. The chirality of these centres is strongly correlated with the conformation of the molecules due to heteroatom hyperconjugation effects." @default.
• W1995437229 created "2016-06-24" @default.
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• W1995437229 date "2014-07-30" @default.
• W1995437229 modified "2023-10-18" @default.
• W1995437229 title "Stable Hemiaminals with a Cyano Group and a Triazole Ring" @default.
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• W1995437229 doi "https://doi.org/10.3390/molecules190811160" @default.
• W1995437229 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6271600" @default.
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