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- W1995445833 abstract "The isotachophoretic behavior of aromatic nucleus-containing quaternary ammonium ions was studied in the presence of a neutral ligand, α-cyclodextrin. Due to the interaction of cyclodextrin with the hydrophobic aromatic nucleus, isomeric ammonium ions containing, e.g., an o-, m-, or p-disubstituted benzene ring, were satisfactorily separated. In the absence of cyclodextrin, the separation of the isomers was poor. A theoretical approach was also used in order to evaluate the binding equilibrium constant (K) between the analyte ion and α-cyclodextrin through an isotachophoretic measurement. The binding constants (logK) with (o-, m-, and p-methylbenzyl)trimethylammonium ions were found to be 0.8, 1.1, and 1.6, respectively." @default.
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- W1995445833 date "1986-11-01" @default.
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- W1995445833 title "Isotachophoretic Analysis of Quaternary Ammonium Ions by Using α-Cyclodextrin as Complex-Forming Agent" @default.
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- W1995445833 doi "https://doi.org/10.1246/bcsj.59.3459" @default.
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