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- W1995484216 abstract "The first total synthesis of (−)-xialenon A was achieved via enantioselective transannular desymmetrisation of a substituted cycloctene oxide using an organolithium/(−)-α-isosparteine combination. Oxidation of the resulting bicyclo[3.3.0]octanol gave an enone which underwent stereoselective conjugate allylation; subsequent α′-hydroxylation on the more hindered face of a derived enone using hypervalent iodine chemistry led to the natural product." @default.
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- W1995484216 date "2003-12-01" @default.
- W1995484216 modified "2023-10-09" @default.
- W1995484216 title "Synthesis of (−)-xialenon A by enantioselective α-deprotonation-rearrangement of a meso-epoxide" @default.
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- W1995484216 doi "https://doi.org/10.1016/j.tet.2003.09.023" @default.
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