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- W1995488506 abstract "The well-known rate equation by Waite for describing the competition between geminate and bulk recombination of reactants created in pairs in condensed phase was derived by a stochastic approach. Starting from a bivariant master equation for the probability to find the reactive system with definite reactant and geminate-pair numbers, rate equations for the reactant and pair concentrations were obtained as a deterministic approximation. These equations can be combined and yield Waite's equation. The presented approach also allows one to meet situations where fluctuations affect the reaction kinetics." @default.
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- W1995488506 date "1990-07-01" @default.
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- W1995488506 title "Interplay between pair and bulk recombination. A stochastic approach to Waite's equation" @default.
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- W1995488506 doi "https://doi.org/10.1016/0301-0104(90)80080-h" @default.
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