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- W1995492950 abstract "Angle- and temperature-dependent surface extended x-ray-absorption fine-structure measurements for the $frac{p4g(2ifmmodetimeselsetexttimesfi{}2)mathrm{N}}{mathrm{Ni}(100)}$ structure reveal a strong local vibrational anisotropy of the fivefold-bonded N atoms. At room temperature we find clear evidence for anharmonic vibrations of N relative to its four in-plane Ni neighbors while the vibrations along the fifth bond remain harmonic. This is directly linked to the strong surface reconstruction induced by the chemisorption process. The out-of-plane vibration of the N atom is discussed in terms of an Einstein model." @default.
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- W1995492950 date "1988-05-30" @default.
- W1995492950 modified "2023-10-09" @default.
- W1995492950 title "Vibrational Anisotropy and Anharmonicity of N Atoms Bonded to Ni(100)" @default.
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- W1995492950 doi "https://doi.org/10.1103/physrevlett.60.2327" @default.
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