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- W1995554368 abstract "A regio- and steroselective conversion of the totally synthetic 3α, 18-di-O-benzyl-17-nor-14-aphidicolen-16-one (5), into (±)-aphidicolin 1, by hydroxylation of the 2-methylidenebicyclo[3.2.1] oct-3-ene derivative 6 is described. Compound 5 was a key intermediate in our previously described total synthesis of 2, which represented a formal synthesis of 1." @default.
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- W1995554368 date "1988-06-15" @default.
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- W1995554368 title "A Total Synthesis of (�)- Aphidicolin: Regio- and stereoselective conversion of 3?,18-Di-O-benzyl-17-nor-14-aphidicolen-16-one into (�)-aphidicolin" @default.
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- W1995554368 doi "https://doi.org/10.1002/hlca.19880710423" @default.
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