FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995589096> ?p ?o ?g. }

• W1995589096 endingPage "10971" @default.
• W1995589096 startingPage "10963" @default.
• W1995589096 abstract "Thermodynamic properties of aqueous solutions of poly[(vinyl alcohol)-co-(vinyl sulfate)] (PVAS) copolymer polyelectrolytes with divalent transition metal (Co(II), Ni(II), and Cu(II)) counterions have been determined by the gel deswelling method in the concentration range of 0.0005-0.12 mol of counterion/kg of water (0.09-9 w/w% of the polymer). The influence of the chemical nature of the counterion as well as the effect of the composition of the copolymer from small to medium linear charge density have been systematically studied. Solvent activity, reduced osmotic pressure, the Flory-Huggins pair interaction parameter, rational osmotic coefficients, and degrees of dissociation were calculated from the measured data. No difference could have been observed between the three counterions. Reduced osmotic pressure curves are found to be convex from above, as for Na+ counterions studied previously, which is contrary to the usual behavior of neutral polymers. Intercepts are increasing, and the calculated apparent molar masses and degrees of dissociation at infinite dilution are decreasing with increasing linear charge density of the polyelectrolytes. The pair interaction parameters show a considerable negative deviation from linearity, except for the high volume fraction region. From the differences, concentration dependence of degrees of dissociation could have been calculated. The values at infinite dilution are in good agreement with those obtained from the intercepts of the reduced osmotic pressure curves. Degrees of dissociation seem to decrease approximately linearly with increasing concentration and reach zero at finite concentrations. Rational osmotic coefficients have been calculated in three different ways, both regarding and neglecting the change in the degrees of dissociation." @default.
• W1995589096 created "2016-06-24" @default.
• W1995589096 creator A5017412943 @default.
• W1995589096 creator A5075769147 @default.
• W1995589096 date "2006-11-15" @default.
• W1995589096 modified "2023-10-03" @default.
• W1995589096 title "Role of Linear Charge Density and Counterion Quality in Thermodynamic Properties of Strong Acid Type Polyelectrolytes: Divalent Transition Metal Cations" @default.
• W1995589096 cites W1577471489 @default.
• W1995589096 cites W1982601865 @default.
• W1995589096 cites W1988432536 @default.
• W1995589096 cites W1993715822 @default.
• W1995589096 cites W2002038726 @default.
• W1995589096 cites W2006586203 @default.
• W1995589096 cites W2006745004 @default.
• W1995589096 cites W2014511781 @default.
• W1995589096 cites W2017373329 @default.
• W1995589096 cites W2023578572 @default.
• W1995589096 cites W2030586569 @default.
• W1995589096 cites W2031119128 @default.
• W1995589096 cites W2042561641 @default.
• W1995589096 cites W2051824888 @default.
• W1995589096 cites W2054189981 @default.
• W1995589096 cites W2054410130 @default.
• W1995589096 cites W2071619414 @default.
• W1995589096 cites W2075755854 @default.
• W1995589096 cites W2077452230 @default.
• W1995589096 cites W2077486500 @default.
• W1995589096 cites W2084878876 @default.
• W1995589096 cites W2088426874 @default.
• W1995589096 cites W2150094083 @default.
• W1995589096 cites W2398725760 @default.
• W1995589096 cites W4235737499 @default.
• W1995589096 cites W4237760804 @default.
• W1995589096 cites W4237947233 @default.
• W1995589096 doi "https://doi.org/10.1021/la061642o" @default.
• W1995589096 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17154572" @default.
• W1995589096 hasPublicationYear "2006" @default.
• W1995589096 type Work @default.
• W1995589096 sameAs 1995589096 @default.
• W1995589096 citedByCount "8" @default.
• W1995589096 countsByYear W19955890962016 @default.
• W1995589096 countsByYear W19955890962019 @default.
• W1995589096 countsByYear W19955890962021 @default.
• W1995589096 crossrefType "journal-article" @default.
• W1995589096 hasAuthorship W1995589096A5017412943 @default.
• W1995589096 hasAuthorship W1995589096A5075769147 @default.
• W1995589096 hasConcept C102931765 @default.
• W1995589096 hasConcept C113196181 @default.
• W1995589096 hasConcept C121332964 @default.
• W1995589096 hasConcept C145148216 @default.
• W1995589096 hasConcept C147789679 @default.
• W1995589096 hasConcept C150708132 @default.
• W1995589096 hasConcept C153356533 @default.
• W1995589096 hasConcept C178790620 @default.
• W1995589096 hasConcept C184651966 @default.
• W1995589096 hasConcept C185592680 @default.
• W1995589096 hasConcept C34814092 @default.
• W1995589096 hasConcept C43617362 @default.
• W1995589096 hasConcept C521977710 @default.
• W1995589096 hasConcept C55493867 @default.
• W1995589096 hasConcept C62520636 @default.
• W1995589096 hasConcept C74884574 @default.
• W1995589096 hasConcept C9603476 @default.
• W1995589096 hasConcept C96618451 @default.
• W1995589096 hasConcept C97355855 @default.
• W1995589096 hasConceptScore W1995589096C102931765 @default.
• W1995589096 hasConceptScore W1995589096C113196181 @default.
• W1995589096 hasConceptScore W1995589096C121332964 @default.
• W1995589096 hasConceptScore W1995589096C145148216 @default.
• W1995589096 hasConceptScore W1995589096C147789679 @default.
• W1995589096 hasConceptScore W1995589096C150708132 @default.
• W1995589096 hasConceptScore W1995589096C153356533 @default.
• W1995589096 hasConceptScore W1995589096C178790620 @default.
• W1995589096 hasConceptScore W1995589096C184651966 @default.
• W1995589096 hasConceptScore W1995589096C185592680 @default.
• W1995589096 hasConceptScore W1995589096C34814092 @default.
• W1995589096 hasConceptScore W1995589096C43617362 @default.
• W1995589096 hasConceptScore W1995589096C521977710 @default.
• W1995589096 hasConceptScore W1995589096C55493867 @default.
• W1995589096 hasConceptScore W1995589096C62520636 @default.
• W1995589096 hasConceptScore W1995589096C74884574 @default.
• W1995589096 hasConceptScore W1995589096C9603476 @default.
• W1995589096 hasConceptScore W1995589096C96618451 @default.
• W1995589096 hasConceptScore W1995589096C97355855 @default.
• W1995589096 hasIssue "26" @default.
• W1995589096 hasLocation W19955890961 @default.
• W1995589096 hasLocation W19955890962 @default.
• W1995589096 hasOpenAccess W1995589096 @default.
• W1995589096 hasPrimaryLocation W19955890961 @default.
• W1995589096 hasRelatedWork W1545915031 @default.
• W1995589096 hasRelatedWork W1995589096 @default.
• W1995589096 hasRelatedWork W2019444816 @default.
• W1995589096 hasRelatedWork W2031475041 @default.
• W1995589096 hasRelatedWork W2047759587 @default.
• W1995589096 hasRelatedWork W2163565120 @default.
• W1995589096 hasRelatedWork W2312520532 @default.
• W1995589096 hasRelatedWork W2601992461 @default.
• W1995589096 hasRelatedWork W3100217474 @default.

• next