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- W1995629903 abstract "The novel bis(iminophosphorano)methanes CH 2 [P{ NP( S)(OR) 2 }Ph 2 ] 2 (R = Ph ( 1a ), Et ( 1b )) have been obtained by oxydation of dppm with the corresponding thiophosphorylated azides (RO) 2 P( S)N 3 . Deprotonation of 1a,b with KH generates the methanide species KCH[P{ NP( S)(OR) 2 }Ph 2 ] 2 (R = Ph ( 2a ), Et ( 2b )). The ruthenium(II) dimer [{Ru(η 6 - p -cymene)(μ-Cl)Cl} 2 ] reacts with 2a,b to afford the cationic complexes [Ru(η 6 - p -cymene)(κ 3 - C , N , S -CH[P{ NP( S)(OR) 2 }Ph 2 ] 2 )] + (R = Ph ( 3a ), Et ( 3b )), via selective κ 3 - C , N , S -coordination of the bis(iminophosphorano)methanide anions to ruthenium. The structure of [Ru(η 6 - p -cymene)(κ 3 - C , N , S -CH[P{ NP( S)(OEt) 2 }Ph 2 ] 2 )][PF 6 ] ( 3b ) has been confirmed by single-crystal X-ray crystallography. Deprotonation of complexes 3a,b with NaH leads to the neutral carbene derivatives [Ru(η 6 - p -cymene)(κ 2 - C , N -C[P{ NP( S)(OR) 2 }Ph 2 ] 2 )] (R = Ph ( 4a ), Et ( 4b ))." @default.
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- W1995629903 date "2005-04-01" @default.
- W1995629903 modified "2023-10-14" @default.
- W1995629903 title "Novel (η6-arene)-ruthenium(II) complexes containing bis(iminophosphorano)methanide and methandiide ligands" @default.
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- W1995629903 doi "https://doi.org/10.1016/j.jorganchem.2004.12.034" @default.
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