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- W1995641986 abstract "Density matrix theory has been applied to obtain rate parameters for the interconversion between [1,2,5]thiadiazolo[3,4-e]benzofurazan-3-oxide and [1,2,5]thiadiazolo[3,4-e]benzofurazan-l-oxide (I), and for that between 7-methyl[1,2,3]triazolo[4,5-e]benzofurazan-3-oxide and 7-methyl[1,2,3]triazolo[4,5-ϵ]benzo-furazan-l-oxide (II). These systems show a superposition of two spectra of the AB type when exchange is slow; a single average AB spectrum is obtained under conditions of fast exchange. The activation parameters for the interconversions are ΔH‡ = 92± 2 kJ mol−1, ΔS‡ = 13±5 J mol−1°C−1 for system (I), and ΔH‡ = 91 ± 1 kJ mol−1, ΔS‡ = 19 ± 3 J mo−1 ΔCt-1 for system (II)." @default.
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- W1995641986 date "1971-02-01" @default.
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- W1995641986 title "Exchange effects on NMR spectra for the benzofurazan oxide series: Cases of the type AB ⇌ A′B′" @default.
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- W1995641986 doi "https://doi.org/10.1016/0022-2364(71)90029-1" @default.
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