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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995647515> ?p ?o ?g. }

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• W1995647515 abstract "X-ray photoelectron spectroscopy (XPS) studies have been performed to explore the effect of mixed valent (3 + /4 + ) Pr substitution for the divalent Ca on the electronic and crystal structure of the Bi-based cuprates. Metal-insulator transition is observed on a well-characterized Pr-doped Bi2Sr2Ca1 − xPrxCu2Oy system with different Pr concentrations (x = 0 to 0.5). Core-level shifts of the Bi, Sr, and Ca to higher binding energies are observed with increase in Pr content. XPS core-level spectra of Sr, 3d and Ca 2p show that Pr occupies both the Sr and Ca sites in the structure. The deconvolution of Cu 2p main peak shows a decrease in the intensity of the higher binding energy shoulder which implies a decrease in Cu valence due to the hole filling caused by the extra electrons from Pr." @default.
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• W1995647515 date "1998-05-01" @default.
• W1995647515 modified "2023-10-13" @default.
• W1995647515 title "XPS study of Tc depression and M-I transition in Bi2Sr2Ca1−xPrxCu2Oy system" @default.
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• W1995647515 doi "https://doi.org/10.1016/s0022-3697(97)00134-0" @default.
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