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- W1995667415 abstract "Deprotonation of N-ethylidene-tert-butylamine with lithium diisopropylamide and subsequent condensation with ethyl trifluoroacetate gives 4-tert-butylamino-1,1,1-trifluorobut-3-en-2-one. An exchange of the amino substituent occurs when the latter compound is treated with anilines under mildly acidic conditions. When heated in the presence of phosphoryl trichloride, the resulting 4-anilino-1,1,1-trifluorobut-3-en-2-ones undergo an N → ortho shift of the side chain followed by cyclization and dehydration to afford 2-(trifluoromethyl)quinolines." @default.
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- W1995667415 date "1996-03-01" @default.
- W1995667415 modified "2023-10-18" @default.
- W1995667415 title "2-(Trifluoromethyl)quinolines from anilines: A novel mode of isomerization and cyclization" @default.
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- W1995667415 doi "https://doi.org/10.1016/0040-4020(96)00168-8" @default.
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