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• W1995689741 abstract "Abstract Transient‐pulse experiments in temporal‐analysis‐of‐product (TAP) and conventional mode were performed to determine elementary reaction steps involved in the methane steam reforming reaction over Rh/Al 2 O 3 and Rh/12 CeO 2 –Al 2 O 3 . TAP pulse experiments demonstrated that both catalysts dissociate methane at 773 K leading to hydrogen, carbon, and CH x adspecies. Conventional transient pulse experiments with alternating methane/argon and water pulses with a delay between them of 86, 73, and 5 s, respectively, showed that the reactivity of adspecies over the promoted and nonpromoted catalysts decrease with time. Ceria catalyzes the oxidation of carbon species by water." @default.
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• W1995689741 date "2014-08-22" @default.
• W1995689741 modified "2023-10-18" @default.
• W1995689741 title "Transient Mechanistic Studies of Methane Steam Reforming over Ceria-Promoted Rh/Al₂O₃Catalysts" @default.
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• W1995689741 doi "https://doi.org/10.1002/cctc.201402388" @default.
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