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• W1995693800 abstract "There is a need to develop highly Cu2+ selective materials which can potentially remediate copper contaminated soils and water. Here we show that several highly charged synthetic swelling mica-type clays are highly selective for copper exchange. The synthetic micas have cation exchange capacities (CECs), which are close to their theoretical values. Both Na-saturated and Mg-saturated micas were investigated for Cu ion exchange selectivity. Ion exchange isotherms and Kielland plots were constructed using the equilibrated solution analyses. From these studies it was found that Na-4-mica and Na-3-mica could selectively exchange copper at lower concentrations from solution, whereas Na-2-mica sample performed better by showing Cu ion exchange selectively to almost its capacity. The EPR spectra of Cu-exchanged micas coincide with the mica’s charge characteristics that predict increased binding strength of exchangeable Cu in Na-4-mica and Na-3-mica than in Na-2-mica." @default.
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• W1995693800 date "2007-12-01" @default.
• W1995693800 modified "2023-10-14" @default.
• W1995693800 title "Highly Charged Swelling Mica-Type Clays for Selective Cu Exchange" @default.
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• W1995693800 doi "https://doi.org/10.1021/es070854k" @default.
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