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- W1995725938 abstract "Sorai et al. (Chem. Phys. 18 (1976) 199) observed that the spin transition temperature in [Fe x Zn 1- x (2-pic) 3 ]Cl 2 ·C 2 H 5 OH varies linearly with iron concentration and the slope of the temperature dependence curve of the high-spin content becomes less steep with decreasing concentration. This dilution effect on the high-spin(rightleftarrows)low-spin transition is studied on the basis of the ligand field theory by taking account of the coupling between d electrons of iron and a lattice strain. The calculated temperature dependence of the high-spin content for various iron concentration reproduces the essential features of the observed results including the linear dependence of the spin transition temperature on the concentration." @default.
- W1995725938 created "2016-06-24" @default.
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- W1995725938 date "1980-11-15" @default.
- W1995725938 modified "2023-10-16" @default.
- W1995725938 title "The Effect of Iron Concentration on the High-Spin(rightleftarrows)Low-Spin Transitions in Iron Compounds" @default.
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- W1995725938 doi "https://doi.org/10.1143/jpsj.49.1806" @default.
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