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• W1995730266 abstract "We have measured the vapour pressure of oxygen in Y1Ba2Cu3Ox as a function of x at constant temperature between 450°C and650°C for pressures between 10 m Torr and 1000 Torr. From these vapour pressure curves we have determined (∂x∂μ)T (μ is the chemical potential), a thermodynamic response function analogous to the compressibility and specific heat. (∂x∂μ)T is a quantity which is sensitive to the oxygen configuration and which can be calculated by any candidate theory on the thermodynamics of oxygen. So, the measured (∂x∂μ)T curves should help in the search to determine the correct model for oxygen thermodynamics in Y1Ba2Cu3Ox. In this paper we use a simple quasi-chemical approximation with an empirical x and T dependent on-site energy to accurately fit the vapour pressure curves. This fit provides a fairly simple method to empirically reproduce the vapour pressure as a function of x and T, which should prove useful in materials preparation." @default.
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• W1995730266 date "1991-05-01" @default.
• W1995730266 modified "2023-09-27" @default.
• W1995730266 title "Thermodynamics of oxygen in Y1Ba2Cu3Ox between 450°C and 650°C" @default.
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• W1995730266 doi "https://doi.org/10.1016/0921-4534(91)90722-b" @default.
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