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• W1995747009 abstract "Complexes of general formula TpxCu (Tpx = homoscorpionate ligand) have been employed as catalysts for the insertion of ethyl diazoacetate into C−H bonds of a variety of hydrocarbons and ethers, in moderate to high yields:  tertiary, secondary, and primary C−H bonds have been functionalized by this methodology. Particularly interesting is the homologation of O-methyl groups in ethers, which has been achieved for a group of substrates. The existence of electron-withdrawing groups in the Tpx ligand seems to be crucial for the activity and the selectivity of the catalyst." @default.
• W1995747009 created "2016-06-24" @default.
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• W1995747009 date "2003-09-01" @default.
• W1995747009 modified "2023-10-17" @default.
• W1995747009 title "Functionalization of Carbon−Hydrogen Bonds of Hydrocarbons and Ethers via Carbene Insertion with Copper(I)−Homoscorpionate Catalysts" @default.
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• W1995747009 doi "https://doi.org/10.1021/om034002e" @default.
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