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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1995749425> ?p ?o ?g. }

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• W1995749425 abstract "In the title compound, [Co(C(10)H(8)N(2))(3)][Co(C(7)H(3)NO(4))(2)](2)(ClO(4))·0.5C(3)H(7)NO·1.3H(2)O, the Co(III) atom in the complex cation is pseudoocta-hedrally coordinated by six N atoms of three chelating bipyridine ligands. The Co(III) atom in the complex anion is coordinated by two pyridine N atoms and four carboxyl-ate O atoms of two doubly deprotonated pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral geometry. One dimethyl-formamide solvent mol-ecule and two water mol-ecules are half-occupied and one water mol-ecule is 0.3-occupied. O-H⋯O hydrogen bonds link the water mol-ecules, the perchlorate anions and the complex anions. π-π inter-actions between the pyridine rings of the complex anions are also observed [centroid-centroid distance = 3.804 (3) Å]." @default.
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• W1995749425 date "2012-09-01" @default.
• W1995749425 modified "2023-09-26" @default.
• W1995749425 title "Tris(2,2′-bipyridine-κ²<i>N</i>,<i>N</i>′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ³<i>O</i>²,<i>N</i>,<i>O</i>⁶)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate" @default.
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• W1995749425 doi "https://doi.org/10.1107/s1600536812037208" @default.
• W1995749425 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3470129" @default.
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